JEE AdvancedChemistryCompounds Containing NitrogenMCQ+3 / −1
Amongst the compounds given, the one that would from a brilliant coloured dye on treatment with in dil. followed by addition to an alkaline solution of -naphthlol is
- A

- B

- C

- D

View written solutionFree
Correct answer: C
-
What reaction is being tested?
Treatment with and dilute generates nitrous acid, which converts a primary aromatic amine into a diazonium salt at low temperature:
This diazonium salt then couples with alkaline -naphthol to give a brightly coloured azo dye:
-
Which type of compound can do this?
The compound must be a primary aromatic amine such as aniline or a substituted aniline.
- Primary aromatic amine gives stable diazonium salt azo dye forms.
- Primary aliphatic amine diazonium salt unstable, decomposes.
- Secondary/tertiary amines do not give this azo-coupling test in the same way.
- Amides/nitro compounds/etc. do not directly diazotize to form the dye.
-
Conclusion
Therefore, among the given options, the correct compound must be the one corresponding to a primary aromatic amine. Since the stored correct answer is C, option C must be that compound.
-
Final answer
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