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Compounds Containing Nitrogen question

2009 · Shift 1 · Q20
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  2. /JEE Advanced
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  4. /Compounds Containing Nitrogen
  5. /2009 · Shift 1 · Q20

Compounds Containing Nitrogen question

2009 · Shift 1 · Q20

JEE AdvancedChemistryCompounds Containing NitrogenMCQ+3 / −1

Match each of the compounds in Column I with its characteristic reaction(s) in Column II.

Column I Column II
(A) CH3CH2CH2CNC{H_3}C{H_2}C{H_2}CNCH3​CH2​CH2​CN (P) Reduction with Pd−C/H2Pd - C/{H_2}Pd−C/H2​
(B) CH3CH2OCOCH3C{H_3}C{H_2}OCOC{H_3}CH3​CH2​OCOCH3​ (Q) Reduction with SnCl2/HClSnC{l_2}/HClSnCl2​/HCl
(C) CH3−CH=CH−CH2OHC{H_3} - CH = CH - C{H_2}OHCH3​−CH=CH−CH2​OH (R) Development of foul smell on treatment with chloroform and alcoholic KOHKOHKOH
(D) CH3CH2CH2CH2NH2C{H_3}C{H_2}C{H_2}C{H_2}N{H_2}CH3​CH2​CH2​CH2​NH2​ (S) Reduction with diisobutylaluminium hydride (DIBAL-H)
(T) Alkaline hydrolysis

  1. A
    (A)→(P),(Q),(S),(T);(B)→(Q),(T);(C)→(P);(D)→(S)\mathrm{(A)\to(P),(Q),(S),(T);(B)\to(Q),(T);(C)\to(P);(D)\to(S)}(A)→(P),(Q),(S),(T);(B)→(Q),(T);(C)→(P);(D)→(S)
  2. B
    (A)→(Q),(R),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R)\mathrm{(A)\to(Q), (R), (S),(T);(B)\to(S),(T);(C)\to(P);(D)\to(R)}(A)→(Q),(R),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R)
  3. C
    (A)→(P),(R),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R),(T)\mathrm{(A)\to(P),(R),(S),(T);(B)\to(S),(T);(C)\to(P);(D)\to(R), (T)}(A)→(P),(R),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R),(T)
  4. D
    (A)→(P),(Q),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R)\mathrm{(A)\to(P),(Q),(S),(T);(B)\to(S),(T);(C)\to(P);(D)\to(R)}(A)→(P),(Q),(S),(T);(B)→(S),(T);(C)→(P);(D)→(R)
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