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Chemical Bonding and Molecular Structure question

2017 · Shift 1 · Q9
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Chemical Bonding and Molecular Structure question

2017 · Shift 1 · Q9

JEE AdvancedChemistryChemical Bonding and Molecular StructureNumerical+3 / −1
Among H2,He2+,Li2,Be2,B2,C2,N2,O2−{H_2},H{e_2}^ + ,L{i_2},B{e_2},{B_2},{C_2},{N_2},O_2^ -H2​,He2​+,Li2​,Be2​,B2​,C2​,N2​,O2−​ and F2,{F_2},F2​, the number of diamagnetic species is (Atomic numbers : H=1,He=2,Li=3,Be=4,B=5,C=6,N=7,O=8,F=9H = 1,He = 2,Li = 3,Be = 4,B = 5,C = 6,N = 7,O = 8,F = 9H=1,He=2,Li=3,Be=4,B=5,C=6,N=7,O=8,F=9)
Numerical answer
View written solutionFree

Correct answer: 6

  1. We determine diamagnetism using Molecular Orbital Theory.

  2. A species is diamagnetic if all electrons are paired in its molecular orbitals.

  3. Check each species one by one.


1. H2H_2H2​

Total electrons =2= 2=2.

MO filling: σ1s2\sigma_{1s}^2σ1s2​ All electrons are paired.

⇒H2\Rightarrow H_2⇒H2​ is diamagnetic.


2. He2+He_2^+He2+​

Total electrons =2+2−1=3= 2+2-1=3=2+2−1=3? Actually each He has 2 electrons, so: 2+2−1=32+2-1=32+2−1=3 This is incorrect counting for cation; for He2+He_2^+He2+​ total electrons are 2+2−1=32+2-1=32+2−1=3 MO filling: σ1s2 σ1s∗1\sigma_{1s}^2\,\sigma_{1s}^{*1}σ1s2​σ1s∗1​ One unpaired electron is present.

⇒He2+\Rightarrow He_2^+⇒He2+​ is paramagnetic.


3. Li2Li_2Li2​

Each Li has 3 electrons. Core 1s1s1s electrons are paired and do not affect magnetic nature; valence electrons = 2.

MO filling (valence): σ2s2\sigma_{2s}^2σ2s2​ All electrons are paired.

⇒Li2\Rightarrow Li_2⇒Li2​ is diamagnetic.


4. Be2Be_2Be2​

Valence electrons =4= 4=4.

MO filling: σ2s2 σ2s∗2\sigma_{2s}^2\,\sigma_{2s}^{*2}σ2s2​σ2s∗2​ All electrons are paired.

⇒Be2\Rightarrow Be_2⇒Be2​ is diamagnetic.


5. B2B_2B2​

Valence electrons =6= 6=6. For B2,C2,N2B_2, C_2, N_2B2​,C2​,N2​ ordering is: σ2s<σ2s∗<π2px=π2py<σ2pz\sigma_{2s}<\sigma_{2s}^*<\pi_{2p_x}=\pi_{2p_y}<\sigma_{2p_z}σ2s​<σ2s∗​<π2px​​=π2py​​<σ2pz​​

Filling: σ2s2 σ2s∗2 π2px1 π2py1\sigma_{2s}^2\,\sigma_{2s}^{*2}\,\pi_{2p_x}^1\,\pi_{2p_y}^1σ2s2​σ2s∗2​π2px​1​π2py​1​ Two unpaired electrons are present.

⇒B2\Rightarrow B_2⇒B2​ is paramagnetic.


6. C2C_2C2​

Valence electrons =8= 8=8.

Filling: σ2s2 σ2s∗2 π2px2 π2py2\sigma_{2s}^2\,\sigma_{2s}^{*2}\,\pi_{2p_x}^2\,\pi_{2p_y}^2σ2s2​σ2s∗2​π2px​2​π2py​2​ All electrons are paired.

⇒C2\Rightarrow C_2⇒C2​ is diamagnetic.


7. N2N_2N2​

Valence electrons =10= 10=10.

Filling: σ2s2 σ2s∗2 π2px2 π2py2 σ2pz2\sigma_{2s}^2\,\sigma_{2s}^{*2}\,\pi_{2p_x}^2\,\pi_{2p_y}^2\,\sigma_{2p_z}^2σ2s2​σ2s∗2​π2px​2​π2py​2​σ2pz​2​ All electrons are paired.

⇒N2\Rightarrow N_2⇒N2​ is diamagnetic.


8. O2−O_2^-O2−​

For O2,F2O_2, F_2O2​,F2​ ordering is: σ2s<σ2s∗<σ2pz<π2px=π2py<π2px∗=π2py∗\sigma_{2s}<\sigma_{2s}^*<\sigma_{2p_z}<\pi_{2p_x}=\pi_{2p_y}<\pi_{2p_x}^*=\pi_{2p_y}^*σ2s​<σ2s∗​<σ2pz​​<π2px​​=π2py​​<π2px​∗​=π2py​∗​

O2O_2O2​ has 12 valence electrons, so O2−O_2^-O2−​ has 13 valence electrons.

Filling: σ2s2 σ2s∗2 σ2pz2 π2px2 π2py2 π2px∗2 π2py∗1\sigma_{2s}^2\,\sigma_{2s}^{*2}\,\sigma_{2p_z}^2\,\pi_{2p_x}^2\,\pi_{2p_y}^2\,\pi_{2p_x}^{*2}\,\pi_{2p_y}^{*1}σ2s2​σ2s∗2​σ2pz​2​π2px​2​π2py​2​π2px​∗2​π2py​∗1​ One unpaired electron is present.

⇒O2−\Rightarrow O_2^-⇒O2−​ is paramagnetic.


9. F2F_2F2​

Valence electrons =14= 14=14.

Filling: σ2s2 σ2s∗2 σ2pz2 π2px2 π2py2 π2px∗2 π2py∗2\sigma_{2s}^2\,\sigma_{2s}^{*2}\,\sigma_{2p_z}^2\,\pi_{2p_x}^2\,\pi_{2p_y}^2\,\pi_{2p_x}^{*2}\,\pi_{2p_y}^{*2}σ2s2​σ2s∗2​σ2pz​2​π2px​2​π2py​2​π2px​∗2​π2py​∗2​ All electrons are paired.

⇒F2\Rightarrow F_2⇒F2​ is diamagnetic.


10. Count diamagnetic species

Diamagnetic species are: H2, Li2, Be2, C2, N2, F2H_2,\ Li_2,\ Be_2,\ C_2,\ N_2,\ F_2H2​, Li2​, Be2​, C2​, N2​, F2​

Total number: 666

Hence, the number of diamagnetic species is 6\boxed{6}6​

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