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Correct answer: 6
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We determine diamagnetism using Molecular Orbital Theory.
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A species is diamagnetic if all electrons are paired in its molecular orbitals.
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Check each species one by one.
1.
Total electrons .
MO filling: All electrons are paired.
is diamagnetic.
2.
Total electrons ? Actually each He has 2 electrons, so: This is incorrect counting for cation; for total electrons are MO filling: One unpaired electron is present.
is paramagnetic.
3.
Each Li has 3 electrons. Core electrons are paired and do not affect magnetic nature; valence electrons = 2.
MO filling (valence): All electrons are paired.
is diamagnetic.
4.
Valence electrons .
MO filling: All electrons are paired.
is diamagnetic.
5.
Valence electrons . For ordering is:
Filling: Two unpaired electrons are present.
is paramagnetic.
6.
Valence electrons .
Filling: All electrons are paired.
is diamagnetic.
7.
Valence electrons .
Filling: All electrons are paired.
is diamagnetic.
8.
For ordering is:
has 12 valence electrons, so has 13 valence electrons.
Filling: One unpaired electron is present.
is paramagnetic.
9.
Valence electrons .
Filling: All electrons are paired.
is diamagnetic.
10. Count diamagnetic species
Diamagnetic species are:
Total number:
Hence, the number of diamagnetic species is
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