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Periodic Table and Periodicity question

2001 · Q100
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Periodic Table and Periodicity question

2001 · Q100

NEETChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Correct order of 1st ionization potential among following elements Be, B, C, N, O is
  1. A
    B < Be < C < O < N
  2. B
    B < Be < C < N < O
  3. C
    Be < B < C < N < O
  4. D
    Be < B < C < O < N
View written solutionFree

Correct answer: A

Be – 1s22s2;

B – 1s22s22p1;

C – 1s22s22p2;

N – 1s22s22p3;

O – 1s22s22p4.

IP increases along the period. But IP of Be > B. Further IP of O < N because atoms with fully or partly filled orbitals are most stable and hence have high ionisation energy.

As in case of boron, 2p1 electron have to be removed to get B+(1s2 2s2) from B(1s2 2s2 2p1), while in case of Be (1s22s2) electron have to be removed to get Be+ (1s22s1). p electron can be removed more easily than s electron so the energy required to remove electron will be less in case of boron.

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