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Periodic Table and Periodicity question

2000 · Q108
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Periodic Table and Periodicity question

2000 · Q108

NEETChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Which statement is wrong ?
  1. A
    Bond energy of F2 > Cl2
  2. B
    Electronegativity of F > Cl
  3. C
    F is more oxidising than Cl
  4. D
    Electron affinity of Cl > F
View written solutionFree

Correct answer: A

Bond energy generally decreases on moving from top to bottom along a group. It happens due to fact that size increases on moving down the group and thus, the two nuclei are far apart and less capable of holding the two atoms together.

But in case of F2 molecule due to more repulsion in between non-bonding electron pair (2p) of two fluorines (due to small size of F-atom) in comparison to non-bonding electron pair (3p) in chlorine, the bond energy of F2 is less than Cl2.

BE(F2) = 158.5 kJ/mole and

BE(Cl2)= 242.6 kJ/mole

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