NEETChemistryP Block ElementsMCQ+4 / −1
The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence
- ABCl3 > BF3 > BBr3
- BBBr3 > BCl3 > BF3
- CBBr3 > BF3 > BCl3
- DBF3 > BCl3 > BBr3
View written solutionFree
Correct answer: B
In BF3, p-p overlap between B and F is
maximum due to identical size and energy of
p-orbitals, so electron deficiency in boron of BF3
is neutralized partially to the maximum extent by
back donation. Also, the tendency to back
donate decreases from F to I. So the order will
be:
BBr3 > BCl3 > BF3
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