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Electrochemistry question

2000 · Q95
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Electrochemistry question

2000 · Q95

NEETChemistryElectrochemistryMCQ+4 / −1
Equivalent conductances of Ba2+ and Cl−-− ions are 127 and 76 ohm−-−1 cm−-−1 eq−-−1 respectively. Equivalent conductance of BaCl2 at infinite dilution is
  1. A
    139.5
  2. B
    101.5
  3. C
    203
  4. D
    279
View written solutionFree

Correct answer: A

According to Kohlrausch’s law, the equivalent conductance of BaCl2 at infinite dilution,

λ\lambda λ∞\infty ∞ of BaCl2 = {1 \over 2}$$\lambda ∞\infty ∞ of Ba2+ + λ\lambda λ∞\infty ∞ of Cl-

⇒\Rightarrow⇒ λ\lambda λ∞\infty ∞ of BaCl2 = 12×127+76{1 \over 2} \times 127 + 7621​×127+76 = 139 5

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