NEETChemistryChemical EquilibriumMCQ+4 / −1
In which of the following equilibrium Kc and Kp are not equal?
- A2NO(g) N2(g) + O2(g)
- BSO2(g) + NO2(g) SO3(g) + NO(g)
- CH2(g) + I2(g) 2HI(g)
- D2C(s) + O2(g) 2CO2(g)
View written solutionFree
Correct answer: D
As we know, Kp = Kc × (RT)ng
So, for reaction having same number of gaseous
moles on reactants and products side will have
same value of Kc and Kp otherwise their values are
different.
For reaction, 2NO(g) N2(g) + O2(g)
ng = 2 – 2 = 0
Kp = Kc × (RT)0
Kp = Kc
For reaction, SO2(g) + NO2(g) SO3(g) + NO(g)
ng = 2 – 2 = 0
Kp = Kc × (RT)0
Kp = Kc
For reaction, H2(g) + I2(g) 2HI(g)
ng = 2 – 2 = 0
Kp = Kc × (RT)0
Kp = Kc
For reaction, H2(g) + I2(g) 2HI(g)
ng = 2 – 2 = 0
Kp = Kc × (RT)0
Kp = Kc
For reaction, 2C(s) + O2(g) 2CO2(g)
ng = 2 – 3 = -1
Kp = Kc × (RT)-1
Kp Kc
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