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Chemical Equilibrium question

2010 · Q128
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Chemical Equilibrium question

2010 · Q128

NEETChemistryChemical EquilibriumMCQ+4 / −1
In which of the following equilibrium Kc and Kp are not equal?
  1. A
    2NO(g) ⇌\rightleftharpoons⇌ N2(g) + O2(g)
  2. B
    SO2(g) + NO2(g) ⇌\rightleftharpoons⇌ SO3(g) + NO(g)
  3. C
    H2(g) + I2(g) ⇌\rightleftharpoons⇌ 2HI(g)
  4. D
    2C(s) + O2(g) ⇌\rightleftharpoons⇌ 2CO2(g)
View written solutionFree

Correct answer: D

As we know, Kp = Kc × (RT)Δ\Delta Δng

So, for reaction having same number of gaseous moles on reactants and products side will have same value of Kc and Kp otherwise their values are different.

For reaction, 2NO(g) ⇌\rightleftharpoons⇌ N2(g) + O2(g)

Δ\Delta Δng = 2 – 2 = 0

⇒\Rightarrow⇒ Kp = Kc × (RT)0

∴\therefore∴ Kp = Kc

For reaction, SO2(g) + NO2(g) ⇌\rightleftharpoons⇌ SO3(g) + NO(g)

Δ\Delta Δng = 2 – 2 = 0

⇒\Rightarrow⇒ Kp = Kc × (RT)0

∴\therefore∴ Kp = Kc

For reaction, H2(g) + I2(g) ⇌\rightleftharpoons⇌ 2HI(g)

Δ\Delta Δng = 2 – 2 = 0

⇒\Rightarrow⇒ Kp = Kc × (RT)0

∴\therefore∴ Kp = Kc

For reaction, H2(g) + I2(g) ⇌\rightleftharpoons⇌ 2HI(g)

Δ\Delta Δng = 2 – 2 = 0

⇒\Rightarrow⇒ Kp = Kc × (RT)0

∴\therefore∴ Kp = Kc

For reaction, 2C(s) + O2(g) ⇌\rightleftharpoons⇌ 2CO2(g)

Δ\Delta Δng = 2 – 3 = -1

⇒\Rightarrow⇒ Kp = Kc × (RT)-1

∴\therefore∴ Kp ≠\ne= Kc

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