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Alcohol Phenols and Ethers question

2010 · Q138
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Alcohol Phenols and Ethers question

2010 · Q138

NEETChemistryAlcohol Phenols and EthersMCQ+4 / −1
Which of the following compounds has the most acidic nature?
  1. A
    AIPMT 2010 Prelims Chemistry - Alcohol, Phenols and Ethers Question 25 English Option 1
  2. B
    AIPMT 2010 Prelims Chemistry - Alcohol, Phenols and Ethers Question 25 English Option 2
  3. C
    AIPMT 2010 Prelims Chemistry - Alcohol, Phenols and Ethers Question 25 English Option 3
  4. D
    AIPMT 2010 Prelims Chemistry - Alcohol, Phenols and Ethers Question 25 English Option 4
View written solutionFree

Correct answer: B

Phenol is most acidic among the given options. In phenol, the electron withdrawing phenyl ring polarises the O-H bond thereby facilitating the release of H+.

In option (A) the -I effect of phenyl ring is diminished by -CH2 group.

Moreover, the phenolate ion is stabilised by resonance.

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