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Work Power and Energy question

2021 · 25 Feb · Shift 1 · Q68
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Work Power and Energy question

2021 · 25 Feb · Shift 1 · Q68

JEE MainPhysicsWork Power and EnergyNumerical+4 / −1
The potential energy (U) of a diatomic molecule is a function dependent on r (interatomic distance) as U=αr10−βr5−3U = {\alpha \over {{r^{10}}}} - {\beta \over {{r^5}}} - 3U=r10α​−r5β​−3 where, α\alphaα and β\betaβ are positive constants. The equilibrium distance between two atoms will be (2αβ)ab{\left( {{{2\alpha } \over \beta }} \right)^{{a \over b}}}(β2α​)ba​, where a = ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 1

  1. For equilibrium, the potential energy must be minimum, so dUdr=0.\frac{dU}{dr}=0.drdU​=0.

Given U=αr10−βr5−3.U=\frac{\alpha}{r^{10}}-\frac{\beta}{r^5}-3.U=r10α​−r5β​−3.

  1. Differentiate with respect to rrr: dUdr=αddr(r−10)−βddr(r−5)\frac{dU}{dr}=\alpha\frac{d}{dr}(r^{-10})-\beta\frac{d}{dr}(r^{-5})drdU​=αdrd​(r−10)−βdrd​(r−5) dUdr=−10αr−11+5βr−6.\frac{dU}{dr}=-10\alpha r^{-11}+5\beta r^{-6}.drdU​=−10αr−11+5βr−6.

So equilibrium condition is −10αr−11+5βr−6=0.-10\alpha r^{-11}+5\beta r^{-6}=0.−10αr−11+5βr−6=0.

  1. Simplify: 5r−11(−2α+βr5)=0.5r^{-11}(-2\alpha+\beta r^5)=0.5r−11(−2α+βr5)=0. Since r≠0r\neq 0r=0, we get −2α+βr5=0-2\alpha+\beta r^5=0−2α+βr5=0 βr5=2α\beta r^5=2\alphaβr5=2α r5=2αβ.r^5=\frac{2\alpha}{\beta}.r5=β2α​.

Hence, r=(2αβ)1/5.r=\left(\frac{2\alpha}{\beta}\right)^{1/5}.r=(β2α​)1/5.

  1. Comparing with the given form (2αβ)a/b,\left(\frac{2\alpha}{\beta}\right)^{a/b},(β2α​)a/b, we get ab=15.\frac{a}{b}=\frac{1}{5}.ba​=51​. Therefore, a=1.a=1.a=1.

  2. Check for minimum: d2Udr2=110αr−12−30βr−7.\frac{d^2U}{dr^2}=110\alpha r^{-12}-30\beta r^{-7}.dr2d2U​=110αr−12−30βr−7. At equilibrium, using βr5=2α\beta r^5=2\alphaβr5=2α, d2Udr2=110αr−12−30(2α)r−12=50αr−12>0,\frac{d^2U}{dr^2}=110\alpha r^{-12}-30(2\alpha)r^{-12}=50\alpha r^{-12}>0,dr2d2U​=110αr−12−30(2α)r−12=50αr−12>0, so it is indeed stable equilibrium.

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