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Heat and Thermodynamics question

2023 · 10 Apr · Shift 1 · Q62
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Heat and Thermodynamics question

2023 · 10 Apr · Shift 1 · Q62

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1

Match List I with List II :

List I List II
(A) 3 Translational degrees of freedom (I) Monoatomic gases
(B) 3 Translational, 2 rotational degrees of freedoms (II) Polyatomic gases
(C) 3 Translational, 2 rotational and 1 vibrational degrees of freedom (III) Rigid diatomic gases
(D) 3 Translational, 3 rotational and more than one vibrational degrees of freedom (IV) Nonrigid diatomic gases

Choose the correct answer from the options given below:

  1. A
    (A)-(I), (B)-(III), (C)-(IV), (D)-(II)
  2. B
    (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
  3. C
    (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
  4. D
    (A)-(I), (B)-(IV), (C)-(III), (D)-(II)
View written solutionFree

Correct answer: A

  1. Identify the molecular degrees of freedom for each type of gas

For gases, the active degrees of freedom are:

  • Translational: always 333
  • Rotational:
    • monoatomic: 000
    • diatomic (rigid): 222
    • nonlinear polyatomic: 333
  • Vibrational:
    • rigid diatomic: ignored
    • nonrigid diatomic: can have 111 vibrational mode considered
    • polyatomic: more than one vibrational mode

  1. Match each entry in List I

(A) 3 translational degrees of freedom

This corresponds to a monoatomic gas, because monoatomic molecules have only translational motion.

So, (A)→(I)(A) \to (I)(A)→(I)


(B) 3 translational, 2 rotational degrees of freedom

This is the case for a rigid diatomic gas.

So, (B)→(III)(B) \to (III)(B)→(III)


(C) 3 translational, 2 rotational and 1 vibrational degrees of freedom

This corresponds to a nonrigid diatomic gas, where vibrational motion is also present.

So, (C)→(IV)(C) \to (IV)(C)→(IV)


(D) 3 translational, 3 rotational and more than one vibrational degrees of freedom

This corresponds to polyatomic gases.

So, (D)→(II)(D) \to (II)(D)→(II)


  1. Final matching

Thus the correct matching is:

(A)−(I), (B)−(III), (C)−(IV), (D)−(II)(A)-(I),\ (B)-(III),\ (C)-(IV),\ (D)-(II)(A)−(I), (B)−(III), (C)−(IV), (D)−(II)

This matches Option A.


  1. Comparison with stored answer

Stored correct answer: A

My derived answer: A

So, the derived answer agrees with the stored correct answer.

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