JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Match List I with List II :
| List I | List II | ||
|---|---|---|---|
| (A) | 3 Translational degrees of freedom | (I) | Monoatomic gases |
| (B) | 3 Translational, 2 rotational degrees of freedoms | (II) | Polyatomic gases |
| (C) | 3 Translational, 2 rotational and 1 vibrational degrees of freedom | (III) | Rigid diatomic gases |
| (D) | 3 Translational, 3 rotational and more than one vibrational degrees of freedom | (IV) | Nonrigid diatomic gases |
Choose the correct answer from the options given below:
- A(A)-(I), (B)-(III), (C)-(IV), (D)-(II)
- B(A)-(IV), (B)-(III), (C)-(II), (D)-(I)
- C(A)-(IV), (B)-(II), (C)-(I), (D)-(III)
- D(A)-(I), (B)-(IV), (C)-(III), (D)-(II)
View written solutionFree
Correct answer: A
- Identify the molecular degrees of freedom for each type of gas
For gases, the active degrees of freedom are:
- Translational: always
- Rotational:
- monoatomic:
- diatomic (rigid):
- nonlinear polyatomic:
- Vibrational:
- rigid diatomic: ignored
- nonrigid diatomic: can have vibrational mode considered
- polyatomic: more than one vibrational mode
- Match each entry in List I
(A) 3 translational degrees of freedom
This corresponds to a monoatomic gas, because monoatomic molecules have only translational motion.
So,
(B) 3 translational, 2 rotational degrees of freedom
This is the case for a rigid diatomic gas.
So,
(C) 3 translational, 2 rotational and 1 vibrational degrees of freedom
This corresponds to a nonrigid diatomic gas, where vibrational motion is also present.
So,
(D) 3 translational, 3 rotational and more than one vibrational degrees of freedom
This corresponds to polyatomic gases.
So,
- Final matching
Thus the correct matching is:
This matches Option A.
- Comparison with stored answer
Stored correct answer: A
My derived answer: A
So, the derived answer agrees with the stored correct answer.
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