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Heat and Thermodynamics question

2017 · 9 Apr · Shift 1 · Q62
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Heat and Thermodynamics question

2017 · 9 Apr · Shift 1 · Q62

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
N moles of a diatomic gas in a cylinder are at a temperature T. Heat is supplied to the cylinder such that the temperature remains constant but n moles of the diatomic gas get converted into monoatomic gas. What is the change in the total kinetic energy of the gas ?
  1. A
    12{1 \over 2}21​ nRT
  2. B
    0
  3. C
    32{3 \over 2}23​ nRT
  4. D
    52{5 \over 2}25​ nRT
View written solutionFree

Correct answer: B

  1. Use kinetic theory for total translational kinetic energy

For an ideal gas, the total kinetic energy of molecular translation depends only on the number of moles and temperature:

K=32NRTK = \frac{3}{2}NRTK=23​NRT

This is true whether the gas is monoatomic or diatomic, because translational kinetic energy is always

32RT per mole.\frac{3}{2}RT \text{ per mole}.23​RT per mole.

  1. Initial state

Initially, there are NNN moles of diatomic gas at temperature TTT.

So initial total kinetic energy is

Ki=32NRTK_i = \frac{3}{2}NRTKi​=23​NRT

  1. Final state

Temperature remains constant, and nnn moles of diatomic gas are converted into monoatomic gas.

But the total number of moles remains NNN; only the nature of nnn moles changes from diatomic to monoatomic.

Since translational kinetic energy depends only on total moles and temperature,

Kf=32NRTK_f = \frac{3}{2}NRTKf​=23​NRT

  1. Change in total kinetic energy

ΔK=Kf−Ki=32NRT−32NRT=0\Delta K = K_f - K_i = \frac{3}{2}NRT - \frac{3}{2}NRT = 0ΔK=Kf​−Ki​=23​NRT−23​NRT=0

  1. Check options
  • A: 12nRT\frac{1}{2}nRT21​nRT ❌
  • B: 000 ✅
  • C: 32nRT\frac{3}{2}nRT23​nRT ❌
  • D: 52nRT\frac{5}{2}nRT25​nRT ❌

Therefore, the correct answer is:

0\boxed{0}0​

So Option B is correct.

  1. Comparison with stored answer

Stored correct answer: A

My derived answer: B

The stored answer likely confuses total internal energy with total kinetic (translational) energy. If the question asks specifically for total kinetic energy of the gas, then for an ideal gas at constant temperature it remains unchanged, regardless of whether molecules are monoatomic or diatomic.

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