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Heat and Thermodynamics question

2016 · Shift 0 · Q55
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Heat and Thermodynamics question

2016 · Shift 0 · Q55

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
′n′'n'′n′ moles of an ideal gas undergoes a process A→BA \to BA→B as shown in the figure. The maximum temperature of the gas during the process will be : JEE Main 2016 (Offline) Physics - Heat and Thermodynamics Question 392 English
  1. A
    9P0V02nR{{9{P_0}{V_0}} \over {2nR}}2nR9P0​V0​​
  2. B
    9P0V0nR{{9{P_0}{V_0}} \over {nR}}nR9P0​V0​​
  3. C
    9P0V04nR{{9{P_0}{V_0}} \over {4nR}}4nR9P0​V0​​
  4. D
    3P0V02nR{{3{P_0}{V_0}} \over {2nR}}2nR3P0​V0​​
View written solutionFree

Correct answer: C

  1. Use the ideal gas law

For an ideal gas, PV=nRT ⇒ T=PVnR.PV=nRT \,\Rightarrow\, T=\frac{PV}{nR}.PV=nRT⇒T=nRPV​.

So, along the given process on the PPP-VVV diagram, the temperature is proportional to the product PVPVPV.

  1. Equation of the path A→BA \to BA→B

From the graph, the straight line joins the intercepts A:(V0,3P0),B:(3V0,0).A:(V_0,3P_0), \qquad B:(3V_0,0).A:(V0​,3P0​),B:(3V0​,0).

Hence its equation is obtained from two-point form.

Slope: m=0−3P03V0−V0=−3P02V0.m=\frac{0-3P_0}{3V_0-V_0}=\frac{-3P_0}{2V_0}.m=3V0​−V0​0−3P0​​=2V0​−3P0​​.

Therefore, P−3P0=−3P02V0(V−V0).P-3P_0=\frac{-3P_0}{2V_0}(V-V_0).P−3P0​=2V0​−3P0​​(V−V0​).

Simplifying, P=9P02−3P02V0V.P=\frac{9P_0}{2}-\frac{3P_0}{2V_0}V.P=29P0​​−2V0​3P0​​V.

  1. Write temperature as a function of volume

Using T=PVnR,T=\frac{PV}{nR},T=nRPV​, we get T(V)=1nR(9P02V−3P02V0V2).T(V)=\frac{1}{nR}\left(\frac{9P_0}{2}V-\frac{3P_0}{2V_0}V^2\right).T(V)=nR1​(29P0​​V−2V0​3P0​​V2).

So, T(V)=3P02nR(3V−V2V0).T(V)=\frac{3P_0}{2nR}\left(3V-\frac{V^2}{V_0}\right).T(V)=2nR3P0​​(3V−V0​V2​).

  1. Maximize T(V)T(V)T(V)

Differentiate with respect to VVV: dTdV=1nR(9P02−3P0V0V).\frac{dT}{dV}=\frac{1}{nR}\left(\frac{9P_0}{2}-\frac{3P_0}{V_0}V\right).dVdT​=nR1​(29P0​​−V0​3P0​​V).

Set it equal to zero: 9P02−3P0V0V=0.\frac{9P_0}{2}-\frac{3P_0}{V_0}V=0.29P0​​−V0​3P0​​V=0.

92=3VV0\frac{9}{2}=3\frac{V}{V_0}29​=3V0​V​

VV0=32.\frac{V}{V_0}=\frac{3}{2}.V0​V​=23​.

So the temperature is maximum at V=3V02.V=\frac{3V_0}{2}.V=23V0​​.

  1. Find corresponding pressure

Substitute into the line equation: P=9P02−3P02V0⋅3V02P=\frac{9P_0}{2}-\frac{3P_0}{2V_0}\cdot \frac{3V_0}{2}P=29P0​​−2V0​3P0​​⋅23V0​​

P=9P02−9P04=9P04.P=\frac{9P_0}{2}-\frac{9P_0}{4}=\frac{9P_0}{4}.P=29P0​​−49P0​​=49P0​​.

  1. Compute maximum temperature

Tmax⁡=PVnR=1nR(9P04)(3V02)T_{\max}=\frac{PV}{nR}=\frac{1}{nR}\left(\frac{9P_0}{4}\right)\left(\frac{3V_0}{2}\right)Tmax​=nRPV​=nR1​(49P0​​)(23V0​​)

Tmax⁡=27P0V08nR.T_{\max}=\frac{27P_0V_0}{8nR}.Tmax​=8nR27P0​V0​​.

  1. Compare with options

Given options are:

  • A: 9P0V02nR\dfrac{9P_0V_0}{2nR}2nR9P0​V0​​
  • B: 9P0V0nR\dfrac{9P_0V_0}{nR}nR9P0​V0​​
  • C: 9P0V04nR\dfrac{9P_0V_0}{4nR}4nR9P0​V0​​
  • D: 3P0V02nR\dfrac{3P_0V_0}{2nR}2nR3P0​V0​​

Our derived value is 27P0V08nR.\boxed{\frac{27P_0V_0}{8nR}}.8nR27P0​V0​​​. This does not match any option.

So the stored correct answer C\text{C}C is not consistent with the straight-line graph described above. If the figure indeed has endpoints A(V0,3P0)A(V_0,3P_0)A(V0​,3P0​) and B(3V0,0)B(3V_0,0)B(3V0​,0), then the correct maximum temperature should be 27P0V08nR.\boxed{\frac{27P_0V_0}{8nR}}.8nR27P0​V0​​​.

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