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Heat and Thermodynamics question

2005 · Shift 0 · Q149
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  5. /2005 · Shift 0 · Q149

Heat and Thermodynamics question

2005 · Shift 0 · Q149

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
A gaseous mixture consists of 16g16g16g of helium and 16g16g16g of oxygen. The ratio CpCv{{Cp} \over {{C_v}}}Cv​Cp​ of the mixture is
  1. A
    1.621.621.62
  2. B
    1.591.591.59
  3. C
    1.541.541.54
  4. D
    1.41.41.4
View written solutionFree

Correct answer: A

  1. Find moles of each gas
  • For helium: nHe=164=4 moln_{\text{He}}=\frac{16}{4}=4\ \text{mol}nHe​=416​=4 mol

  • For oxygen: nO2=1632=0.5 moln_{\text{O}_2}=\frac{16}{32}=0.5\ \text{mol}nO2​​=3216​=0.5 mol

  1. Use molar heat capacities at constant volume
  • Helium is a monoatomic gas: CV,He=3R2,CP,He=5R2C_{V,\text{He}}=\frac{3R}{2}, \qquad C_{P,\text{He}}=\frac{5R}{2}CV,He​=23R​,CP,He​=25R​

  • Oxygen is a diatomic gas (at ordinary temperature): CV,O2=5R2,CP,O2=7R2C_{V,\text{O}_2}=\frac{5R}{2}, \qquad C_{P,\text{O}_2}=\frac{7R}{2}CV,O2​​=25R​,CP,O2​​=27R​

  1. Calculate total CVC_VCV​ of the mixture

CV=nHe(3R2)+nO2(5R2)C_V=n_{\text{He}}\left(\frac{3R}{2}\right)+n_{\text{O}_2}\left(\frac{5R}{2}\right)CV​=nHe​(23R​)+nO2​​(25R​)

CV=4⋅3R2+0.5⋅5R2C_V=4\cdot \frac{3R}{2}+0.5\cdot \frac{5R}{2}CV​=4⋅23R​+0.5⋅25R​

CV=6R+1.25R=7.25RC_V=6R+1.25R=7.25RCV​=6R+1.25R=7.25R

  1. Calculate total CPC_PCP​ of the mixture

CP=nHe(5R2)+nO2(7R2)C_P=n_{\text{He}}\left(\frac{5R}{2}\right)+n_{\text{O}_2}\left(\frac{7R}{2}\right)CP​=nHe​(25R​)+nO2​​(27R​)

CP=4⋅5R2+0.5⋅7R2C_P=4\cdot \frac{5R}{2}+0.5\cdot \frac{7R}{2}CP​=4⋅25R​+0.5⋅27R​

CP=10R+1.75R=11.75RC_P=10R+1.75R=11.75RCP​=10R+1.75R=11.75R

  1. Find the ratio γ=CPCV\gamma=\dfrac{C_P}{C_V}γ=CV​CP​​

γ=11.75R7.25R=11.757.25\gamma=\frac{11.75R}{7.25R}=\frac{11.75}{7.25}γ=7.25R11.75R​=7.2511.75​

γ≈1.621\gamma\approx 1.621γ≈1.621

So, CPCV≈1.62\boxed{\frac{C_P}{C_V}\approx 1.62}CV​CP​​≈1.62​

  1. Option check
  • A: 1.621.621.62 ✅
  • B: 1.591.591.59 ❌
  • C: 1.541.541.54 ❌
  • D: 1.41.41.4 ❌

Therefore, the correct answer is A.

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