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Dual Nature of Radiation question

2025 · 22 Jan · Shift 1 · Q62
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  5. /2025 · 22 Jan · Shift 1 · Q62

Dual Nature of Radiation question

2025 · 22 Jan · Shift 1 · Q62

JEE MainPhysicsDual Nature of RadiationMCQ+4 / −1
An electron in the ground state of the hydrogen atom has the orbital radius of 5.3×10−11 m5.3 \times 10^{-11} \mathrm{~m}5.3×10−11 m while that for the electron in third excited state is 8.48×10−10 m8.48 \times 10^{-10} \mathrm{~m}8.48×10−10 m. The ratio of the de Broglie wavelengths of electron in the ground state to that in the excited state is
  1. A
    4
  2. B
    3
  3. C
    9
  4. D
    16
View written solutionFree

Correct answer: 1/4

  1. Use Bohr model relation for radius

    For hydrogen atom, rn=n2a0r_n = n^2 a_0rn​=n2a0​ where a0=5.3×10−11 ma_0 = 5.3 \times 10^{-11}\,\text{m}a0​=5.3×10−11m.

    The given excited-state radius is 8.48×10−10 m8.48 \times 10^{-10}\,\text{m}8.48×10−10m which corresponds to the third excited state, i.e. n=4n=4n=4.

    Check: r4=42a0=16a0=16(5.3×10−11)=8.48×10−10 mr_4 = 4^2 a_0 = 16a_0 = 16(5.3\times 10^{-11}) = 8.48\times 10^{-10}\,\text{m}r4​=42a0​=16a0​=16(5.3×10−11)=8.48×10−10m So this is consistent.

  2. Use de Broglie standing-wave condition

    For an electron in Bohr orbit, 2πrn=nλn2\pi r_n = n\lambda_n2πrn​=nλn​ Therefore, λn=2πrnn\lambda_n = \frac{2\pi r_n}{n}λn​=n2πrn​​

    Since rn=n2a0r_n = n^2 a_0rn​=n2a0​, λn=2πn2a0n=2πna0\lambda_n = \frac{2\pi n^2 a_0}{n} = 2\pi n a_0λn​=n2πn2a0​​=2πna0​

    Hence, λn∝n\lambda_n \propto nλn​∝n

  3. Find the ratio

    Ground state: n=1n=1n=1

    Third excited state: n=4n=4n=4

    Therefore, λ1λ4=14\frac{\lambda_1}{\lambda_4} = \frac{1}{4}λ4​λ1​​=41​

  4. Compare with options

    The required ratio of de Broglie wavelengths of electron in ground state to that in the excited state is 14\boxed{\frac{1}{4}}41​​

    None of the given options 4,3,9,164, 3, 9, 164,3,9,16 match this value.

  5. Likely issue in the question/options

    If the question intended the ratio of wavelengths in the excited state to the ground state, then λ4λ1=4\frac{\lambda_4}{\lambda_1} = 4λ1​λ4​​=4 which matches option A.

    So the stored answer appears to match the inverse ratio, not the ratio actually asked.

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