- AThe standard state of a pure gas is the pure gas at a pressure of 1 bar and temperature 273 K.
- Bis zero for .
- Cis zero for .
- DThe term 'standard state' implies that the temperature is 0°C.
View written solutionFree
Correct answer: B
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Recall the definition of standard state
The standard state of a substance means its most stable form at a given temperature and at a pressure of 1 bar.
Important point: standard state does not fix the temperature to or . The temperature must always be specified separately, commonly .
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Check option A
Option A says:
The standard state of a pure gas is the pure gas at a pressure of 1 bar and temperature 273 K.
This is incorrect because standard state requires pressure bar, but temperature is not necessarily .
So, A is false.
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Check option B
Option B says:
is zero for .
The standard enthalpy of formation of an element in its most stable standard state is taken as zero at that temperature.
At , oxygen in its standard state is still .
Therefore,
So, B is true.
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Check option C
Option C says:
is zero for .
This is incorrect because the standard state of oxygen at is , not atomic oxygen .
Since is not the standard state, its enthalpy of formation is not zero.
So, C is false.
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Check option D
Option D says:
The term 'standard state' implies that the temperature is .
This is incorrect. Standard state does not imply any fixed temperature like .
So, D is false.
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Conclusion
Only option B is correct.
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