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Thermodynamics question

2022 · 29 Jul · Shift 1 · Q18
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Thermodynamics question

2022 · 29 Jul · Shift 1 · Q18

JEE MainChemistryThermodynamicsNumerical+4 / −1
When 600 mL of 0.2 M HNO3HNO_3HNO3​ is mixed with 400 mL400 \mathrm{~mL}400 mL of 0.1 M NaOHNaOHNaOH solution in a flask, the rise in temperature of the flask is ‾\underline{\hspace{2cm}}​×10−2 ∘C\times 10^{-2}{ }\,^{\circ} \mathrm{C}×10−2∘C. (Enthalpy of neutralisation =57 kJ mol−1=57 \mathrm{~kJ} \mathrm{~mol}^{-1}=57 kJ mol−1 and Specific heat of water =4.2 JK−1 g−1=4.2 \,\mathrm{JK}^{-1} \mathrm{~g}^{-1}=4.2JK−1 g−1) (Neglect heat capacity of flask)
Numerical answer
View written solutionFree

Correct answer: 54

  1. Write the reaction

HNO3+NaOH→NaNO3+H2OHNO_3 + NaOH \rightarrow NaNO_3 + H_2OHNO3​+NaOH→NaNO3​+H2​O

For strong acid–strong base neutralisation, heat released is:

ΔHneut=57 kJ mol−1\Delta H_{\text{neut}} = 57\,\text{kJ mol}^{-1}ΔHneut​=57kJ mol−1

This is per mole of water formed (or per mole of acid-base neutralised).


  1. Calculate moles of acid and base

For HNO3HNO_3HNO3​:

nHNO3=0.2×0.6=0.12 moln_{HNO_3} = 0.2 \times 0.6 = 0.12\,\text{mol}nHNO3​​=0.2×0.6=0.12mol

For NaOHNaOHNaOH:

nNaOH=0.1×0.4=0.04 moln_{NaOH} = 0.1 \times 0.4 = 0.04\,\text{mol}nNaOH​=0.1×0.4=0.04mol

Since the reaction is 1:11:11:1, the limiting reagent is NaOHNaOHNaOH.

So, moles neutralised:

n=0.04 moln = 0.04\,\text{mol}n=0.04mol


  1. Heat evolved

q=n×57 kJ=0.04×57=2.28 kJq = n \times 57\,\text{kJ} = 0.04 \times 57 = 2.28\,\text{kJ}q=n×57kJ=0.04×57=2.28kJ

q=2280 Jq = 2280\,\text{J}q=2280J


  1. Mass of solution

Total volume mixed:

600 mL+400 mL=1000 mL600\,\text{mL} + 400\,\text{mL} = 1000\,\text{mL}600mL+400mL=1000mL

Assuming density of solution ≈1 g mL−1\approx 1\,\text{g mL}^{-1}≈1g mL−1,

m=1000 gm = 1000\,\text{g}m=1000g


  1. Use heat relation

q=mcΔTq = mc\Delta Tq=mcΔT

Given:

c=4.2 J g−1K−1c = 4.2\,\text{J g}^{-1}\text{K}^{-1}c=4.2J g−1K−1

So,

ΔT=qmc=22801000×4.2\Delta T = \frac{q}{mc} = \frac{2280}{1000 \times 4.2}ΔT=mcq​=1000×4.22280​

ΔT=22804200=0.542857 ∘C\Delta T = \frac{2280}{4200} = 0.542857\,^\circ\text{C}ΔT=42002280​=0.542857∘C

ΔT≈0.54 ∘C=54×10−2 ∘C\Delta T \approx 0.54\,^\circ\text{C} = 54 \times 10^{-2}\,^\circ\text{C}ΔT≈0.54∘C=54×10−2∘C


  1. Final integer answer

The blank is:

54\boxed{54}54​

This means the rise in temperature is

54×10−2 ∘C54 \times 10^{-2}\,^\circ\text{C}54×10−2∘C

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