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Thermodynamics question

2020 · 9 Jan · Shift 2 · Q10
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Thermodynamics question

2020 · 9 Jan · Shift 2 · Q10

JEE MainChemistryThermodynamicsMCQ+4 / −1
The true statement amongst the following is :
  1. A
    S is a function of temperature but Δ\DeltaΔ S is not a function of temperature.
  2. B
    Both S and Δ\DeltaΔ S are not functions of temperature.
  3. C
    Both Δ\DeltaΔ S and S are functions of temperature.
  4. D
    S is not a function of temperature but Δ\DeltaΔ S is a function of temperature.
View written solutionFree

Correct answer: C

  1. Recall what entropy depends on

    Entropy SSS is a state function. For a given system, its value depends on the thermodynamic state, and hence it generally depends on variables such as temperature, pressure, volume, etc.

    Therefore, in general, S=S(T,P)orS=S(T,V)S = S(T, P) \quad \text{or} \quad S = S(T, V)S=S(T,P)orS=S(T,V) so SSS is a function of temperature.

  2. Check whether entropy change ΔS\Delta SΔS depends on temperature

    Entropy change between two states is ΔS=∫δqrevT\Delta S = \int \frac{\delta q_{\text{rev}}}{T}ΔS=∫Tδqrev​​

    For example, for heating a substance from T1T_1T1​ to T2T_2T2​ at constant heat capacity, ΔS=nCln⁡(T2T1)\Delta S = nC \ln\left(\frac{T_2}{T_1}\right)ΔS=nCln(T1​T2​​)

    This clearly shows that ΔS\Delta SΔS depends on temperature (through T1T_1T1​ and T2T_2T2​).

    So ΔS\Delta SΔS is also a function of temperature.

  3. Evaluate each option

    • A: SSS is a function of temperature but ΔS\Delta SΔS is not a function of temperature.
      False, because ΔS\Delta SΔS generally depends on temperature.

    • B: Both SSS and ΔS\Delta SΔS are not functions of temperature.
      False, because both generally depend on temperature.

    • C: Both ΔS\Delta SΔS and SSS are functions of temperature.
      True.

    • D: SSS is not a function of temperature but ΔS\Delta SΔS is a function of temperature.
      False, because SSS does depend on temperature.

  4. Final answer

    The true statement is: C\boxed{\text{C}}C​

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