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Thermodynamics question

2019 · 9 Apr · Shift 1 · Q6
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Thermodynamics question

2019 · 9 Apr · Shift 1 · Q6

JEE MainChemistryThermodynamicsMCQ+4 / −1
Among the following, the set of parameters that represents path function, is : (A) q + w (B) q (C) w (D) H–TS
  1. A
    (B) and (C)
  2. B
    (A) and (D)
  3. C
    (B), (C) and (D)
  4. D
    (A), (B) and (C)
View written solutionFree

Correct answer: A

  1. Identify which quantities are path functions and which are state functions

    • Heat qqq is a path function.
    • Work www is a path function.
    • Their sum q+wq+wq+w equals the change in internal energy: q+w=ΔUq+w=\Delta Uq+w=ΔU Since ΔU\Delta UΔU depends only on initial and final states, it is a state function, not a path function.
    • For H−TSH-TSH−TS: G=H−TSG=H-TSG=H−TS where HHH (enthalpy), TTT (temperature), and SSS (entropy) are state variables, so H−TSH-TSH−TS is also a state function.
  2. Evaluate the given items

    • (A) q+wq+wq+w →\rightarrow→ state function
    • (B) qqq →\rightarrow→ path function
    • (C) www →\rightarrow→ path function
    • (D) H−TSH-TSH−TS →\rightarrow→ state function
  3. Select the correct set

    The path functions are only (B) and (C).

  4. Match with options

    • Option A: (B)(B)(B) and (C)(C)(C) ✔
    • Option B: (A)(A)(A) and (D)(D)(D) ✘
    • Option C: (B),(C)(B), (C)(B),(C) and (D)(D)(D) ✘
    • Option D: (A),(B)(A), (B)(A),(B) and (C)(C)(C) ✘

Therefore, the correct answer is Option A.

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