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Thermodynamics question

2019 · 11 Jan · Shift 2 · Q15
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Thermodynamics question

2019 · 11 Jan · Shift 2 · Q15

JEE MainChemistryThermodynamicsMCQ+4 / −1
The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by Δ\DeltaΔ rGo = A – BT Where A and B are non-zero constants. Which of the following is TRUE about this reaction?
  1. A
    Exothermic if B < 0
  2. B
    Endothermic if A > 0
  3. C
    Exothermic if A > 0 and B < 0
  4. D
    Endothermic if A < 0 and B > 0
View written solutionFree

Correct answer: B

  1. We are given the standard Gibbs energy change:

ΔrG∘=A−BT\Delta_r G^\circ = A - BTΔr​G∘=A−BT

where AAA and BBB are constants.

  1. Use the thermodynamic relation:

ΔrG∘=ΔrH∘−TΔrS∘\Delta_r G^\circ = \Delta_r H^\circ - T\Delta_r S^\circΔr​G∘=Δr​H∘−TΔr​S∘

Comparing with

ΔrG∘=A−BT\Delta_r G^\circ = A - BTΔr​G∘=A−BT

we identify:

ΔrH∘=A,ΔrS∘=B\Delta_r H^\circ = A, \qquad \Delta_r S^\circ = BΔr​H∘=A,Δr​S∘=B

  1. Now determine when the reaction is exothermic or endothermic.
  • Exothermic reaction means:

ΔrH∘<0\Delta_r H^\circ < 0Δr​H∘<0

So here, exothermic means:

A<0A < 0A<0

  • Endothermic reaction means:

ΔrH∘>0\Delta_r H^\circ > 0Δr​H∘>0

So here, endothermic means:

A>0A > 0A>0

  1. Therefore, the sign of BBB is irrelevant for deciding whether the reaction is exothermic or endothermic. Only AAA matters.

  2. Evaluate the options:

  • A: Exothermic if B<0B<0B<0
    False, because exothermicity depends on AAA, not BBB.

  • B: Endothermic if A>0A>0A>0
    True, because ΔrH∘=A\Delta_r H^\circ = AΔr​H∘=A.

  • C: Exothermic if A>0A>0A>0 and B<0B<0B<0
    False, since A>0A>0A>0 implies endothermic, not exothermic.

  • D: Although the printed option appears truncated as “Endothermic if A 0A\ 0A 0”, the meaningful correct statement from thermodynamics is clearly option B.

  1. Hence, the correct answer is:

B\boxed{\text{B}}B​

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