JEE MainChemistryThermodynamicsMCQ+4 / −1
The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by rGo = A – BT Where A and B are non-zero constants. Which of the following is TRUE about this reaction?
- AExothermic if B < 0
- BEndothermic if A > 0
- CExothermic if A > 0 and B < 0
- DEndothermic if A < 0 and B > 0
View written solutionFree
Correct answer: B
- We are given the standard Gibbs energy change:
where and are constants.
- Use the thermodynamic relation:
Comparing with
we identify:
- Now determine when the reaction is exothermic or endothermic.
- Exothermic reaction means:
So here, exothermic means:
- Endothermic reaction means:
So here, endothermic means:
-
Therefore, the sign of is irrelevant for deciding whether the reaction is exothermic or endothermic. Only matters.
-
Evaluate the options:
-
A: Exothermic if
False, because exothermicity depends on , not . -
B: Endothermic if
True, because . -
C: Exothermic if and
False, since implies endothermic, not exothermic. -
D: Although the printed option appears truncated as “Endothermic if ”, the meaningful correct statement from thermodynamics is clearly option B.
- Hence, the correct answer is:
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