JEE MainChemistryStructure of AtomMCQ+4 / −1
Which of the following statements are correct? (A) The electronic configuration of Cr is [Ar] 3d5 4s1. (B) The magnetic quantum number may have a negative value. (C) In the ground state of an atom, the orbitals are filled in order of their increasing energies. (D) The total number of nodes are given by n 2. Choose the most appropriate answer from the options given below :
- A(A), (C) and (D) only
- B(A) and (B) only
- C(A) and (C) only
- D(A), (B) and (C) only
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Correct answer: D
- Check statement (A): Electronic configuration of Cr
Chromium has atomic number .
Its expected configuration by simple Aufbau filling would be: But chromium is an exception due to extra stability of half-filled -subshell: So, (A) is correct.
- Check statement (B): Magnetic quantum number may have a negative value
The magnetic quantum number can take values: Hence it can definitely be negative.
So, (B) is correct.
- Check statement (C): In ground state, orbitals are filled in order of increasing energies
This is the Aufbau principle: in the ground state, electrons occupy orbitals in order of increasing energy.
So, (C) is correct.
- Check statement (D): Total number of nodes are given by
For an orbital:
- Total number of nodes
- Angular nodes
- Radial nodes
Thus total nodes are: So statement (D) saying total nodes are is incorrect.
- Conclusion
Correct statements are:
Therefore, the correct option is:
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