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Solutions question

2023 · 1 Feb · Shift 2 · Q19
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Solutions question

2023 · 1 Feb · Shift 2 · Q19

JEE MainChemistrySolutionsNumerical+4 / −1
20%20 \%20% of acetic acid is dissociated when its 5 g5 \mathrm{~g}5 g is added to 500 mL500 \mathrm{~mL}500 mL of water. The depression in freezing point of such water is ‾\underline{\hspace{2cm}}​×10−3∘C\times 10^{-3}{ }^{\circ} \mathrm{C}×10−3∘C. Atomic mass of C,H\mathrm{C}, \mathrm{H}C,H and O\mathrm{O}O are 12,1 and 16 a.m.u. respectively. [Given : Molal depression constant and density of water are 1.86 K kg mol−11.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}1.86 K kg mol−1 and 1 g cm−31 \mathrm{~g} \mathrm{~cm}^{-3}1 g cm−3 respectively.]
Numerical answer
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Correct answer: 372

  1. Molar mass of acetic acid

Acetic acid is CH3COOH=C2H4O2\mathrm{CH_3COOH} = \mathrm{C_2H_4O_2}CH3​COOH=C2​H4​O2​.

M=2(12)+4(1)+2(16)=24+4+32=60 g mol−1M = 2(12) + 4(1) + 2(16) = 24 + 4 + 32 = 60\ \text{g mol}^{-1}M=2(12)+4(1)+2(16)=24+4+32=60 g mol−1

  1. Moles of acetic acid added

Given mass =5 g= 5\ \text{g}=5 g,

n=560=112 moln = \frac{5}{60} = \frac{1}{12}\ \text{mol}n=605​=121​ mol

  1. Mass of solvent (water)

Volume of water =500 mL= 500\ \text{mL}=500 mL and density =1 g mL−1= 1\ \text{g mL}^{-1}=1 g mL−1,

so mass of water

=500 g=0.5 kg= 500\ \text{g} = 0.5\ \text{kg}=500 g=0.5 kg

  1. Molality before dissociation correction

m=1/120.5=16 mol kg−1m = \frac{1/12}{0.5} = \frac{1}{6}\ \text{mol kg}^{-1}m=0.51/12​=61​ mol kg−1

  1. van't Hoff factor

Acetic acid dissociates as

CH3COOH⇌CH3COO−+H+\mathrm{CH_3COOH \rightleftharpoons CH_3COO^- + H^+}CH3​COOH⇌CH3​COO−+H+

If degree of dissociation is α=20%=0.2\alpha = 20\% = 0.2α=20%=0.2, then for a solute giving 2 particles,

i=1+α=1+0.2=1.2i = 1 + \alpha = 1 + 0.2 = 1.2i=1+α=1+0.2=1.2

  1. Depression in freezing point

ΔTf=iKfm\Delta T_f = i K_f mΔTf​=iKf​m

ΔTf=(1.2)(1.86)(16)\Delta T_f = (1.2)(1.86)\left(\frac{1}{6}\right)ΔTf​=(1.2)(1.86)(61​)

ΔTf=1.2×0.31=0.372 ∘C\Delta T_f = 1.2 \times 0.31 = 0.372\ ^\circ\mathrm{C}ΔTf​=1.2×0.31=0.372 ∘C

  1. Write in the required form

0.372 ∘C=372×10−3 ∘C0.372\ ^\circ\mathrm{C} = 372 \times 10^{-3}\ ^\circ\mathrm{C}0.372 ∘C=372×10−3 ∘C

Therefore, the required integer is:

372\boxed{372}372​

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