- A
- B
- C
- D
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Correct answer: C
-
Identify the anion from the first tests
The compound :
- on treatment with concentrated produces brown fumes
- gives a dark brown ring with in presence of concentrated
These are characteristic tests for the nitrate ion, .
- Brown fumes are due to .
- Brown ring test confirms nitrate.
Therefore, must be a nitrate, so options containing nitrite are rejected.
Hence, eliminate:
- B:
Possible options left:
- A:
- C:
- D:
-
Identify the cation from the test
The solution of in dilute is treated with , giving a precipitate .
In acidic medium, precipitates cations of Group II as sulfides.
Among the remaining options:
- gives black precipitate of
- gives black precipitate of
- is not precipitated in acidic medium in this way (it belongs to later group behavior)
So A is eliminated.
Possible options now:
- C:
- D:
-
Use the confirmatory test for precipitate
The precipitate on treatment with concentrated followed by excess gives a deep blue coloured solution.
This is the characteristic test for :
- dissolves in oxidizing acid like concentrated to form
- then with excess , copper forms the deep blue tetraammine complex:
This deep blue solution is diagnostic of copper.
Lead does not give a deep blue solution with excess ammonia.
-
Conclusion
Therefore, the compound is:
-
Option check
- A: — incorrect
- B: — incorrect
- C: — correct
- D: — incorrect
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