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Practical Organic Chemistry question

2021 · 20 Jul · Shift 1 · Q5
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  5. /2021 · 20 Jul · Shift 1 · Q5

Practical Organic Chemistry question

2021 · 20 Jul · Shift 1 · Q5

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
An inorganic Compound 'X' on treatment with concentrated H2SO4H_2SO_4H2​SO4​ produces brown fumes and gives dark brown ring with FeSO4FeSO_4FeSO4​ in presence of concentrated H2SO4H_2SO_4H2​SO4​. Also Compound 'X' gives precipitate 'Y', when its solution in dilute HClHClHCl is treated with H2SH_2SH2​S gas. The precipitate 'Y' on treatment with concentrated HNO3HNO_3HNO3​ followed by excess of NH4OHNH_4OHNH4​OH further gives deep blue coloured solution, Compound 'X' is :
  1. A
    Co(NO3)2Co(NO_3)_2Co(NO3​)2​
  2. B
    Pb(NO2)2Pb(NO_2)_2Pb(NO2​)2​
  3. C
    Cu(NO3)2Cu(NO_3)_2Cu(NO3​)2​
  4. D
    Pb(NO3)2Pb(NO_3)_2Pb(NO3​)2​
View written solutionFree

Correct answer: C

  1. Identify the anion from the first tests

    The compound XXX:

    • on treatment with concentrated H2SO4H_2SO_4H2​SO4​ produces brown fumes
    • gives a dark brown ring with FeSO4FeSO_4FeSO4​ in presence of concentrated H2SO4H_2SO_4H2​SO4​

    These are characteristic tests for the nitrate ion, NO3−NO_3^-NO3−​.

    • Brown fumes are due to NO2NO_2NO2​.
    • Brown ring test confirms nitrate.

    Therefore, XXX must be a nitrate, so options containing nitrite are rejected.

    Hence, eliminate:

    • B: Pb(NO2)2Pb(NO_2)_2Pb(NO2​)2​

    Possible options left:

    • A: Co(NO3)2Co(NO_3)_2Co(NO3​)2​
    • C: Cu(NO3)2Cu(NO_3)_2Cu(NO3​)2​
    • D: Pb(NO3)2Pb(NO_3)_2Pb(NO3​)2​
  2. Identify the cation from the H2SH_2SH2​S test

    The solution of XXX in dilute HClHClHCl is treated with H2SH_2SH2​S, giving a precipitate YYY.

    In acidic medium, H2SH_2SH2​S precipitates cations of Group II as sulfides.

    Among the remaining options:

    • Cu2+Cu^{2+}Cu2+ gives black precipitate of CuSCuSCuS
    • Pb2+Pb^{2+}Pb2+ gives black precipitate of PbSPbSPbS
    • Co2+Co^{2+}Co2+ is not precipitated in acidic medium in this way (it belongs to later group behavior)

    So A is eliminated.

    Possible options now:

    • C: Cu(NO3)2Cu(NO_3)_2Cu(NO3​)2​
    • D: Pb(NO3)2Pb(NO_3)_2Pb(NO3​)2​
  3. Use the confirmatory test for precipitate YYY

    The precipitate YYY on treatment with concentrated HNO3HNO_3HNO3​ followed by excess NH4OHNH_4OHNH4​OH gives a deep blue coloured solution.

    This is the characteristic test for Cu2+Cu^{2+}Cu2+:

    • CuSCuSCuS dissolves in oxidizing acid like concentrated HNO3HNO_3HNO3​ to form Cu2+Cu^{2+}Cu2+
    • then with excess NH4OHNH_4OHNH4​OH, copper forms the deep blue tetraammine complex:

    Cu2++4NH3→[Cu(NH3)4]2+Cu^{2+} + 4NH_3 \rightarrow [Cu(NH_3)_4]^{2+}Cu2++4NH3​→[Cu(NH3​)4​]2+

    This deep blue solution is diagnostic of copper.

    Lead does not give a deep blue solution with excess ammonia.

  4. Conclusion

    Therefore, the compound XXX is:

    Cu(NO3)2\boxed{Cu(NO_3)_2}Cu(NO3​)2​​

  5. Option check

    • A: Co(NO3)2Co(NO_3)_2Co(NO3​)2​ — incorrect
    • B: Pb(NO2)2Pb(NO_2)_2Pb(NO2​)2​ — incorrect
    • C: Cu(NO3)2Cu(NO_3)_2Cu(NO3​)2​ — correct
    • D: Pb(NO3)2Pb(NO_3)_2Pb(NO3​)2​ — incorrect
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