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Periodic Table and Periodicity question

2025 · 8 Apr · Shift 2 · Q12
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Periodic Table and Periodicity question

2025 · 8 Apr · Shift 2 · Q12

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are two statements: Statement I: H2SeH_2SeH2​Se is more acidic than H2TeH_2TeH2​Te Statement II: H2SeH_2SeH2​Se has higher bond enthalpy for dissociation than H2TeH_2TeH2​Te In the light of the above statements, choose the correct answer from the options given below:
  1. A
    Both Statement I and Statement II are true
  2. B
    Statement I is true but Statement II is false
  3. C
    Both Statement I and Statement II are false
  4. D
    Statement I is false but Statement II is true
View written solutionFree

Correct answer: D

  1. Compare acidity of group 16 hydrides

    The hydrides are: H2O, H2S, H2Se, H2TeH_2O,\, H_2S,\, H_2Se,\, H_2TeH2​O,H2​S,H2​Se,H2​Te

    Down the group, acidity increases because the E−HE-HE−H bond (E=E = E= chalcogen) becomes weaker as atomic size increases.

    Thus, H2O<H2S<H2Se<H2TeH_2O < H_2S < H_2Se < H_2TeH2​O<H2​S<H2​Se<H2​Te in acidic strength.

    Therefore, H2Te is more acidic than H2SeH_2Te \text{ is more acidic than } H_2SeH2​Te is more acidic than H2​Se

    So Statement I: "H2SeH_2SeH2​Se is more acidic than H2TeH_2TeH2​Te" is false.

  2. Compare bond enthalpy of dissociation

    Down group 16, size of the central atom increases, overlap between 1s1s1s orbital of H and the valence orbital of the chalcogen decreases, so the H−EH-EH−E bond becomes weaker.

    Hence bond enthalpy decreases: H−O>H−S>H−Se>H−TeH-O > H-S > H-Se > H-TeH−O>H−S>H−Se>H−Te

    Therefore, bond enthalpy(H−Se)>bond enthalpy(H−Te)\text{bond enthalpy}(H-Se) > \text{bond enthalpy}(H-Te)bond enthalpy(H−Se)>bond enthalpy(H−Te)

    So Statement II: "H2SeH_2SeH2​Se has higher bond enthalpy for dissociation than H2TeH_2TeH2​Te" is true.

  3. Evaluate the options

    • A: Both true  Incorrect
    • B: I true, II false  Incorrect
    • C: Both false  Incorrect
    • D: I false, II true ✓\checkmark✓ Correct
  4. Conclusion

    The correct option is: D\boxed{D}D​

  5. Comparison with stored answer

    Stored correct answer: D

    My derived answer also is D, so they agree.

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