- ABoth Statement I and Statement II are true
- BStatement I is true but Statement II is false
- CBoth Statement I and Statement II are false
- DStatement I is false but Statement II is true
View written solutionFree
Correct answer: D
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Compare acidity of group 16 hydrides
The hydrides are:
Down the group, acidity increases because the bond ( chalcogen) becomes weaker as atomic size increases.
Thus, in acidic strength.
Therefore,
So Statement I: " is more acidic than " is false.
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Compare bond enthalpy of dissociation
Down group 16, size of the central atom increases, overlap between orbital of H and the valence orbital of the chalcogen decreases, so the bond becomes weaker.
Hence bond enthalpy decreases:
Therefore,
So Statement II: " has higher bond enthalpy for dissociation than " is true.
-
Evaluate the options
- A: Both true Incorrect
- B: I true, II false Incorrect
- C: Both false Incorrect
- D: I false, II true Correct
-
Conclusion
The correct option is:
-
Comparison with stored answer
Stored correct answer: D
My derived answer also is D, so they agree.
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