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Periodic Table and Periodicity question

2024 · 4 Apr · Shift 1 · Q16
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Periodic Table and Periodicity question

2024 · 4 Apr · Shift 1 · Q16

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The correct order of first ionization enthalpy values of the following elements is : (A) O (B) N (C) Be (D) F (E) B Choose the correct answer from the options given below :
  1. A
    A<B<D<C<E\mathrm{A}\lt \mathrm{B}\lt \mathrm{D}\lt \mathrm{C}\lt \mathrm{E}A<B<D<C<E
  2. B
    C<E<A<B<D\mathrm{C}\lt \mathrm{E}\lt \mathrm{A}\lt \mathrm{B}\lt \mathrm{D}C<E<A<B<D
  3. C
    E<C<A<B<D\mathrm{E}\lt \mathrm{C}\lt \mathrm{A}\lt \mathrm{B}\lt \mathrm{D}E<C<A<B<D
  4. D
    B<D<C<E<A\mathrm{B}\lt \mathrm{D}\lt \mathrm{C}\lt \mathrm{E}\lt \mathrm{A}B<D<C<E<A
View written solutionFree

Correct answer: C

  1. Identify the elements

Given:

  • A=O\mathrm{A} = \mathrm{O}A=O
  • B=N\mathrm{B} = \mathrm{N}B=N
  • C=Be\mathrm{C} = \mathrm{Be}C=Be
  • D=F\mathrm{D} = \mathrm{F}D=F
  • E=B\mathrm{E} = \mathrm{B}E=B

We need the correct order of first ionization enthalpy.


  1. General trend across Period 2

Across a period, first ionization enthalpy generally increases from left to right due to increasing effective nuclear charge.

So a rough trend in Period 2 is:

B<Be<O<N<F\mathrm{B} < \mathrm{Be} < \mathrm{O} < \mathrm{N} < \mathrm{F}B<Be<O<N<F

But we must include the known exceptions carefully.


  1. Important exceptions

(i) B\mathrm{B}B vs Be\mathrm{Be}Be

  • Be:1s22s2\mathrm{Be}: 1s^2 2s^2Be:1s22s2
  • B:1s22s22p1\mathrm{B}: 1s^2 2s^2 2p^1B:1s22s22p1

The electron removed from boron is a 2p2p2p electron, which is higher in energy and easier to remove than the 2s2s2s electron of beryllium.

Therefore,

I1(B)<I1(Be)I_1(\mathrm{B}) < I_1(\mathrm{Be})I1​(B)<I1​(Be)

(ii) O\mathrm{O}O vs N\mathrm{N}N

  • N:1s22s22p3\mathrm{N}: 1s^2 2s^2 2p^3N:1s22s22p3 (half-filled 2p2p2p subshell, extra stable)
  • O:1s22s22p4\mathrm{O}: 1s^2 2s^2 2p^4O:1s22s22p4

In oxygen, one 2p2p2p orbital has paired electrons, causing extra electron-electron repulsion. So removing one electron from oxygen is easier than from nitrogen.

Therefore,

I1(O)<I1(N)I_1(\mathrm{O}) < I_1(\mathrm{N})I1​(O)<I1​(N)
  1. Now arrange all elements in increasing order

Using the trend and exceptions:

B<Be<O<N<F\mathrm{B} < \mathrm{Be} < \mathrm{O} < \mathrm{N} < \mathrm{F}B<Be<O<N<F

Now convert into the given labels:

  • Boron=E\mathrm{Boron} = \mathrm{E}Boron=E
  • Beryllium=C\mathrm{Beryllium} = \mathrm{C}Beryllium=C
  • Oxygen=A\mathrm{Oxygen} = \mathrm{A}Oxygen=A
  • Nitrogen=B\mathrm{Nitrogen} = \mathrm{B}Nitrogen=B
  • Fluorine=D\mathrm{Fluorine} = \mathrm{D}Fluorine=D

So,

E<C<A<B<D\mathrm{E} < \mathrm{C} < \mathrm{A} < \mathrm{B} < \mathrm{D}E<C<A<B<D
  1. Match with the options

Option C is:

E<C<A<B<D\mathrm{E} < \mathrm{C} < \mathrm{A} < \mathrm{B} < \mathrm{D}E<C<A<B<D

This matches exactly.


  1. Final answer

The correct option is:

C\boxed{\text{C}}C​
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