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Periodic Table and Periodicity question

2021 · 25 Jul · Shift 1 · Q9
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Periodic Table and Periodicity question

2021 · 25 Jul · Shift 1 · Q9

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The ionic radii of K+K^+K+, Na+Na^+Na+, Al3+Al^{3+}Al3+ and Mg2+Mg^{2+}Mg2+ are in the order:
  1. A
    Na+Na^+Na+ < K+K^+K+ < Mg2+Mg^{2+}Mg2+ < Al3+Al^{3+}Al3+
  2. B
    Al3+Al^{3+}Al3+ < Mg2+Mg^{2+}Mg2+ < K+K^+K+ < Na+Na^+Na+
  3. C
    Al3+Al^{3+}Al3+ < Mg2+Mg^{2+}Mg2+ < Na+Na^+Na+ < K+K^+K+
  4. D
    K+K^+K+ < Al3+Al^{3+}Al3+ < Mg2+Mg^{2+}Mg2+ < Na+Na^+Na+
View written solutionFree

Correct answer: C

  1. Identify electronic configurations of the ions
  • K+K^+K+ : 19−1=1819 - 1 = 1819−1=18 electrons ⇒[Ar] \Rightarrow [Ar]⇒[Ar]
  • Na+Na^+Na+ : 11−1=1011 - 1 = 1011−1=10 electrons ⇒[Ne] \Rightarrow [Ne]⇒[Ne]
  • Mg2+Mg^{2+}Mg2+ : 12−2=1012 - 2 = 1012−2=10 electrons ⇒[Ne] \Rightarrow [Ne]⇒[Ne]
  • Al3+Al^{3+}Al3+ : 13−3=1013 - 3 = 1013−3=10 electrons ⇒[Ne] \Rightarrow [Ne]⇒[Ne]

So, Na+Na^+Na+, Mg2+Mg^{2+}Mg2+ and Al3+Al^{3+}Al3+ are isoelectronic (all have 10 electrons).

  1. Compare the isoelectronic ions

For an isoelectronic series, ionic radius decreases as nuclear charge increases, because the same number of electrons are pulled more strongly by more protons.

Nuclear charges are:

  • Na+Na^+Na+ : Z=11Z=11Z=11
  • Mg2+Mg^{2+}Mg2+ : Z=12Z=12Z=12
  • Al3+Al^{3+}Al3+ : Z=13Z=13Z=13

Therefore, Al3+<Mg2+<Na+Al^{3+} < Mg^{2+} < Na^+Al3+<Mg2+<Na+

  1. Compare K+K^+K+ with the above ions

K+K^+K+ has 18 electrons and configuration [Ar][Ar][Ar], so it has one more occupied shell than the [Ne][Ne][Ne] ions. Hence K+K^+K+ is larger than Na+Na^+Na+, Mg2+Mg^{2+}Mg2+, and Al3+Al^{3+}Al3+.

Thus, Al3+<Mg2+<Na+<K+Al^{3+} < Mg^{2+} < Na^+ < K^+Al3+<Mg2+<Na+<K+

  1. Match with the options

This corresponds to Option C.

Al3+<Mg2+<Na+<K+\boxed{Al^{3+} < Mg^{2+} < Na^+ < K^+}Al3+<Mg2+<Na+<K+​

  1. Comparison with stored correct answer

Stored correct answer: C

Our derived answer: C

So they agree.

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