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Periodic Table and Periodicity question

2021 · 26 Feb · Shift 1 · Q4
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Periodic Table and Periodicity question

2021 · 26 Feb · Shift 1 · Q4

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Match List - I with List - II.

List I
Electronic configuration
List II
ΔiH{\Delta _i}HΔi​H in kJ mol−1mo{l^{ - 1}}mol−1
(a) 1s22s21{s^2}2{s^2}1s22s2 (i) 801
(b) 1s22s22p41{s^2}2{s^2}2{p^4}1s22s22p4 (ii) 899
(c) 1s22s22p31{s^2}2{s^2}2{p^3}1s22s22p3 (iii) 1314
(d) 1s22s22p11{s^2}2{s^2}2{p^1}1s22s22p1 (iv) 1402

Choose the most appropriate answer from the options given below :
  1. A
    (a) →\to→ (i), (b) →\to→ (iii), (c) →\to→ (iv), (d) →\to→ (iii)
  2. B
    (a) →\to→ (iv), (b) →\to→ (i), (c) →\to→ (ii), (d) →\to→ (iii)
  3. C
    (a) →\to→ (ii), (b) →\to→ (iii), (c) →\to→ (iv), (d) →\to→ (i)
  4. D
    (a) →\to→ (i), (b) →\to→ (iv), (c) →\to→ (iii), (d) →\to→ (ii)
View written solutionFree

Correct answer: C

  1. Identify the elements from the electronic configurations

    We match each configuration in List I to its element:

    • (a) 1s22s21s^2 2s^21s22s2
      Total electrons =4=4=4 Rightarrow\\RightarrowRightarrow Be
    • (b) 1s22s22p41s^2 2s^2 2p^41s22s22p4
      Total electrons =8=8=8 Rightarrow\\RightarrowRightarrow O
    • (c) 1s22s22p31s^2 2s^2 2p^31s22s22p3
      Total electrons =7=7=7 Rightarrow\\RightarrowRightarrow N
    • (d) 1s22s22p11s^2 2s^2 2p^11s22s22p1
      Total electrons =5=5=5 Rightarrow\\RightarrowRightarrow B
  2. Interpret ΔiH\Delta_i HΔi​H

    Here ΔiH\Delta_i HΔi​H denotes the first ionization enthalpy.

  3. Recall approximate first ionization enthalpies

    Standard values are approximately:

    • Be ≈899 kJ mol−1\approx 899\ \text{kJ mol}^{-1}≈899 kJ mol−1
    • B ≈801 kJ mol−1\approx 801\ \text{kJ mol}^{-1}≈801 kJ mol−1
    • N ≈1402 kJ mol−1\approx 1402\ \text{kJ mol}^{-1}≈1402 kJ mol−1
    • O ≈1314 kJ mol−1\approx 1314\ \text{kJ mol}^{-1}≈1314 kJ mol−1

    These also agree with periodic trends:

    • Be has higher IE than B because Be has a filled 2s22s^22s2 subshell.
    • N has higher IE than O because N has half-filled 2p32p^32p3 stability.
  4. Match List I with List II

    • (a) Be →899\to 899→899 ⇒\Rightarrow⇒ (ii)
    • (b) O →1314\to 1314→1314 ⇒\Rightarrow⇒ (iii)
    • (c) N →1402\to 1402→1402 ⇒\Rightarrow⇒ (iv)
    • (d) B →801\to 801→801 ⇒\Rightarrow⇒ (i)

    So the correct matching is:

    (a)→(ii),(b)→(iii),(c)→(iv),(d)→(i)(a) \to (ii),\quad (b) \to (iii),\quad (c) \to (iv),\quad (d) \to (i)(a)→(ii),(b)→(iii),(c)→(iv),(d)→(i)
  5. Compare with options

    This corresponds to Option C.

  6. Verification with stored answer

    Stored correct answer = C.

    Our derived answer also = C. Hence they agree.

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