Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Hydrocarbons question

2023 · 29 Jan · Shift 1 · Q21
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Hydrocarbons
  5. /2023 · 29 Jan · Shift 1 · Q21

Hydrocarbons question

2023 · 29 Jan · Shift 1 · Q21

JEE MainChemistryHydrocarbonsNumerical+4 / −1
17 mg of a hydrocarbon (M.F. C10H16\mathrm{C_{10}H_{16}}C10​H16​) takes up 8.40 mL of the H 2_22​ gas measured at 0 ∘^\circ∘ C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Hydrocarbons Question 54 English The number of double bond/s present in the hydrocarbon is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 3

  1. Find moles of the hydrocarbon

Given hydrocarbon: C10H16\mathrm{C_{10}H_{16}}C10​H16​

Molar mass: M=10(12)+16(1)=120+16=136 g mol−1M = 10(12) + 16(1) = 120 + 16 = 136\,\text{g mol}^{-1}M=10(12)+16(1)=120+16=136g mol−1

Mass given: 17 mg=0.017 g17\,\text{mg} = 0.017\,\text{g}17mg=0.017g

Moles of hydrocarbon: nHC=0.017136=1.25×10−4 moln_{\text{HC}} = \frac{0.017}{136} = 1.25 \times 10^{-4}\,\text{mol}nHC​=1360.017​=1.25×10−4mol

  1. Find moles of hydrogen absorbed

Hydrogen volume at STP = 8.40 mL8.40\,\text{mL}8.40mL

At STP, 111 mol gas occupies 22400 mL22400\,\text{mL}22400mL.

So, nH2=8.4022400=3.75×10−4 moln_{\mathrm{H_2}} = \frac{8.40}{22400} = 3.75 \times 10^{-4}\,\text{mol}nH2​​=224008.40​=3.75×10−4mol

  1. Relate hydrogen uptake to number of π\piπ bonds reduced

Each double bond consumes 111 mole of H2\mathrm{H_2}H2​ on hydrogenation.

If number of double bonds per molecule is xxx, then x=nH2nHC=3.75×10−41.25×10−4=3x = \frac{n_{\mathrm{H_2}}}{n_{\text{HC}}} = \frac{3.75\times10^{-4}}{1.25\times10^{-4}} = 3x=nHC​nH2​​​=1.25×10−43.75×10−4​=3

So, the hydrocarbon contains: 3\boxed{3}3​ double bonds.

  1. Check with degree of unsaturation

For C10H16\mathrm{C_{10}H_{16}}C10​H16​, degree of unsaturation is IHD=2C+2−H2=2(10)+2−162=62=3\text{IHD} = \frac{2C+2-H}{2} = \frac{2(10)+2-16}{2} = \frac{6}{2} = 3IHD=22C+2−H​=22(10)+2−16​=26​=3

Thus total unsaturation is 333. Since the compound takes up 333 moles of H2\mathrm{H_2}H2​ per mole of hydrocarbon, all three unsaturations are double bonds.

Hence, the number of double bonds is 3\boxed{3}3​.

  1. Comparison with stored answer

Stored correct answer = 333

Derived answer = 333

They agree.

PreviousNext

More from Hydrocarbons

  • The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding rearrangement)2023 · MCQ
  • The major products 'A' and 'B', respectively, are Includes diagram2023 · MCQ
  • Choose the correct set of reagents for the following conversion. trans (Ph−CH=CH−CH3​)→cis(Ph−CH=CH−CH3​)2023 · MCQ
  • A hydrocarbon ' X' with formula C6​H8​ uses two moles of H2​ on catalytic hydrogenation of its one mole. On ozonolysis, 'X' yields two moles of methane dicarbaldehyde. The…2023 · MCQ
  • The major product 'A' of the following given reaction has ​ sp2 hybridized carbon atoms. Includes diagram2022 · Numerical
  • Given below are two statements : Statement I : The presence of weaker π-bonds make alkenes less stable than alkanes. Statement II : The strength of the double bond is greater than that of carbon-carbon single bond. In the light of the…2022 · MCQ
  • Which of the following reagents / reactions will convert 'A' to 'B' ? Includes diagram2022 · MCQ
  • A compound ‘A’ on reaction with ‘X’ and ‘Y’ produces the same major product but different by product 'a' and 'b′. Oxidation of 'a' gives a substance produced by ants. 'X' and 'Y' respectively… Includes diagram2022 · MCQ