JEE MainChemistryHydrocarbonsNumerical+4 / −1
17 mg of a hydrocarbon (M.F. ) takes up 8.40 mL of the H gas measured at 0 C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields
The number of double bond/s present in the hydrocarbon is .
The number of double bond/s present in the hydrocarbon is .Numerical answer
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Correct answer: 3
- Find moles of the hydrocarbon
Given hydrocarbon:
Molar mass:
Mass given:
Moles of hydrocarbon:
- Find moles of hydrogen absorbed
Hydrogen volume at STP =
At STP, mol gas occupies .
So,
- Relate hydrogen uptake to number of bonds reduced
Each double bond consumes mole of on hydrogenation.
If number of double bonds per molecule is , then
So, the hydrocarbon contains: double bonds.
- Check with degree of unsaturation
For , degree of unsaturation is
Thus total unsaturation is . Since the compound takes up moles of per mole of hydrocarbon, all three unsaturations are double bonds.
Hence, the number of double bonds is .
- Comparison with stored answer
Stored correct answer =
Derived answer =
They agree.
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