JEE MainChemistryHydrocarbonsMCQ+4 / −1
Given below are two statements : Statement I : The presence of weaker -bonds make alkenes less stable than alkanes. Statement II : The strength of the double bond is greater than that of carbon-carbon single bond. In the light of the above statements, choose the correct answer from the options given below :
- ABoth Statement I and Statement II are correct.
- BBoth Statement I and Statement II are incorrect.
- CStatement I is correct but Statement II is incorrect.
- DStatement I is incorrect but Statement II is correct.
View written solutionFree
Correct answer: A
-
Analyze Statement I:
Statement I says: The presence of weaker -bonds make alkenes less stable than alkanes.- An alkene contains a double bond, which consists of:
- A -bond is weaker than a -bond because it is formed by sideways overlap of orbitals, which is less effective than head-on overlap.
- Because of the weaker -bond, alkenes are more reactive and thermodynamically less stable than corresponding alkanes.
Therefore, Statement I is correct.
-
Analyze Statement II:
Statement II says: The strength of the double bond is greater than that of carbon-carbon single bond.- A carbon-carbon single bond is one -bond.
- A carbon-carbon double bond has:
- Even though the -bond is weaker than a -bond, the total bond strength of a double bond is still greater than that of a single bond.
- Typical bond energies are:
- Hence, a double bond is stronger than a single bond.
Therefore, Statement II is correct.
-
Conclusion:
Both Statement I and Statement II are correct.So, the correct option is:
-
Comparison with stored answer:
Stored correct answer = A
Derived answer = A
Hence, they agree.
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