Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Hydrocarbons question

2022 · 24 Jun · Shift 2 · Q10
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Hydrocarbons
  5. /2022 · 24 Jun · Shift 2 · Q10

Hydrocarbons question

2022 · 24 Jun · Shift 2 · Q10

JEE MainChemistryHydrocarbonsMCQ+4 / −1
Given below are two statements : Statement I : The presence of weaker π\piπ-bonds make alkenes less stable than alkanes. Statement II : The strength of the double bond is greater than that of carbon-carbon single bond. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    Both Statement I and Statement II are correct.
  2. B
    Both Statement I and Statement II are incorrect.
  3. C
    Statement I is correct but Statement II is incorrect.
  4. D
    Statement I is incorrect but Statement II is correct.
View written solutionFree

Correct answer: A

  1. Analyze Statement I:
    Statement I says: The presence of weaker π\piπ-bonds make alkenes less stable than alkanes.

    • An alkene contains a C=C\mathrm{C=C}C=C double bond, which consists of: 1 σ-bond+1 π-bond1\ \sigma\text{-bond} + 1\ \pi\text{-bond}1 σ-bond+1 π-bond
    • A π\piπ-bond is weaker than a σ\sigmaσ-bond because it is formed by sideways overlap of orbitals, which is less effective than head-on overlap.
    • Because of the weaker π\piπ-bond, alkenes are more reactive and thermodynamically less stable than corresponding alkanes.

    Therefore, Statement I is correct.

  2. Analyze Statement II:
    Statement II says: The strength of the double bond is greater than that of carbon-carbon single bond.

    • A carbon-carbon single bond is one σ\sigmaσ-bond.
    • A carbon-carbon double bond has: 1 σ+1 π1\ \sigma + 1\ \pi1 σ+1 π
    • Even though the π\piπ-bond is weaker than a σ\sigmaσ-bond, the total bond strength of a double bond is still greater than that of a single bond.
    • Typical bond energies are: E(C−C)≈348 kJ mol−1E(\mathrm{C-C}) \approx 348\ \text{kJ mol}^{-1}E(C−C)≈348 kJ mol−1 E(C=C)≈614 kJ mol−1E(\mathrm{C=C}) \approx 614\ \text{kJ mol}^{-1}E(C=C)≈614 kJ mol−1
    • Hence, a double bond is stronger than a single bond.

    Therefore, Statement II is correct.

  3. Conclusion:
    Both Statement I and Statement II are correct.

    So, the correct option is: A\boxed{\text{A}}A​

  4. Comparison with stored answer:
    Stored correct answer = A
    Derived answer = A
    Hence, they agree.

PreviousNext

More from Hydrocarbons

  • Which of the following reagents / reactions will convert 'A' to 'B' ? Includes diagram2022 · MCQ
  • A compound ‘A’ on reaction with ‘X’ and ‘Y’ produces the same major product but different by product 'a' and 'b′. Oxidation of 'a' gives a substance produced by ants. 'X' and 'Y' respectively… Includes diagram2022 · MCQ
  • Major product of the following reaction is Includes diagram2022 · MCQ
  • The product formed in the following reaction. Includes diagram2022 · MCQ
  • Cl∙+CH4​→A+B A and B in the above atmospheric reaction step are :2022 · MCQ
  • The major product in the following reaction Includes diagram2022 · MCQ
  • Product 'A' of following sequence of reactions is Includes diagram2022 · MCQ
  • What will be the major product of following sequence of reactions? Includes diagram2022 · MCQ