In the above reaction, left hand side and right hand side rings are named as '' and 'B' respectively. They undergo ring expansion. The correct statement for this process is:- AFinally both rings will become six membered each.
- BOnly A will become 6 membered.
- CRing expansion can go upto seven membered rings
- DFinally both rings will become five membered each.
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Correct answer: A
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Concept involved: ring expansion in carbocation rearrangement
Ring expansion generally occurs when a strained smaller ring forms a carbocation adjacent to the ring. A bond migrates and the ring expands to give a more stable carbocation and a less strained ring.
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Usual tendency of cyclic systems
- 3-membered and 4-membered rings are highly strained.
- They readily undergo ring expansion.
- Expansion usually continues until a 5-membered or 6-membered ring is formed, because these are much more stable.
- Among these, 6-membered rings are especially stable due to very low ring strain.
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About further expansion
The statement "ring expansion can go upto seven membered rings" is not generally the preferred outcome in such standard rearrangements. Expansion beyond 6-membered rings is not usually favored unless there is some special driving force.
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Inference for rings A and B
Since the question says both left-hand side ring and right-hand side ring undergo ring expansion, the stable final outcome is that both rearrange to six-membered rings.
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Check options
- A: Finally both rings will become six membered each. ✅
- B: Only will become 6 membered. ❌
- C: Ring expansion can go upto seven membered rings. ❌
- D: Finally both rings will become five membered each. ❌
Therefore, the correct option is:
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