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Hydrocarbons question

2019 · 12 Apr · Shift 2 · Q22
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Hydrocarbons question

2019 · 12 Apr · Shift 2 · Q22

JEE MainChemistryHydrocarbonsMCQ+4 / −1
In the following skew conformation of ethane, H'–C–C–H'' dihedral angle is : JEE Main 2019 (Online) 12th April Evening Slot Chemistry - Hydrocarbons Question 109 English
  1. A
    120o
  2. B
    58o
  3. C
    151o
  4. D
    149o
View written solutionFree

Correct answer: D

  1. Key idea: skew conformation in ethane

    In ethane, when viewed along the C−C\mathrm{C-C}C−C bond, the angle between a bond on the front carbon and a bond on the rear carbon is the dihedral angle.

    • Eclipsed conformation: dihedral angle =0∘= 0^\circ=0∘
    • Staggered conformation: dihedral angle =60∘= 60^\circ=60∘
    • Skew conformation: any intermediate angle
  2. Interpreting the given figure

    In the standard skew conformation drawing of ethane used in such questions, the marked hydrogens H′\mathrm{H'}H′ and H′′\mathrm{H''}H′′ are not adjacent in projection; the required angle is the larger torsional separation between them.

    From the geometry of the shown skew arrangement, the acute angle comes out close to 31∘31^\circ31∘. Therefore the corresponding dihedral angle between H′−C−C−H′′\mathrm{H'-C-C-H''}H′−C−C−H′′ is:

    180∘−31∘=149∘180^\circ - 31^\circ = 149^\circ180∘−31∘=149∘

  3. Checking options

    • 120∘120^\circ120∘ : not consistent with the shown bond positions
    • 58∘58^\circ58∘ : close to staggered, but not the marked pair here
    • 151∘151^\circ151∘ : near the value, but not exact
    • 149∘149^\circ149∘ : matches the geometry
  4. Final answer

    149∘\boxed{149^\circ}149∘​

So, the correct option is D.

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