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Hydrocarbons question

2019 · 12 Apr · Shift 1 · Q13
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Hydrocarbons question

2019 · 12 Apr · Shift 1 · Q13

JEE MainChemistryHydrocarbonsMCQ+4 / −1
But-2-ene on reaction with alkaline KMnO4KMnO_4KMnO4​ at elevated temperature followed by acidification will give :
  1. A
    one molecule of CH3CHOCH_3CHOCH3​CHO and one molecule of CH3COOHCH_3COOHCH3​COOH
  2. B
    2 molecules of CH3COOHCH_3COOHCH3​COOH
  3. C
    JEE Main 2019 (Online) 12th April Morning Slot Chemistry - Hydrocarbons Question 111 English Option 3
  4. D
    2 molecules of CH3CHOCH_3CHOCH3​CHO
View written solutionFree

Correct answer: B

  1. Identify the reaction type

    Alkaline KMnO4KMnO_4KMnO4​ at elevated temperature followed by acidification causes oxidative cleavage of the double bond in alkenes.

  2. Write the structure of but-2-ene

    But-2-ene is: CH3−CH=CH−CH3CH_3-CH=CH-CH_3CH3​−CH=CH−CH3​

  3. Apply oxidative cleavage rule

    In oxidative cleavage with hot alkaline KMnO4KMnO_4KMnO4​:

    • Each carbon of the double bond is converted into a carboxylic acid if it has at least one hydrogen attached.
    • If no hydrogen is present, ketone may form.

    In but-2-ene, both double-bond carbons are: −CH=-CH=−CH= So each side has one hydrogen.

  4. Split the molecule across the double bond

    CH3−CH=CH−CH3→CH3COOH+CH3COOHCH_3-CH=CH-CH_3 \rightarrow CH_3COOH + CH_3COOHCH3​−CH=CH−CH3​→CH3​COOH+CH3​COOH

    Thus, the products are two molecules of acetic acid.

  5. Check options

    • A: one molecule of CH3CHOCH_3CHOCH3​CHO and one molecule of CH3COOHCH_3COOHCH3​COOH → incorrect
    • B: 2 molecules of CH3COOHCH_3COOHCH3​COOH → correct
    • D: 2 molecules of CH3CHOCH_3CHOCH3​CHO → incorrect
  6. Final answer

    B: 2 molecules of CH3COOH\boxed{\text{B: 2 molecules of } CH_3COOH}B: 2 molecules of CH3​COOH​

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