- A
- B
- C
- D
View written solutionFree
Correct answer: D
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We need to identify which compound gives acetaldehyde () on heating with aqueous KOH.
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Let us check each option.
Option A:
Acetyl chloride undergoes hydrolysis with aqueous KOH: In alkaline medium, the acid further gives acetate salt. So this does not produce acetaldehyde.
Option B:
Ethyl chloride with aqueous KOH gives nucleophilic substitution: Product is ethanol, not acetaldehyde.
Option C:
1,2-Dichloroethane with aqueous KOH mainly gives ethylene glycol by substitution: This is not acetaldehyde.
Option D:
This is a gem-dihalide. Gem-dihalides on hydrolysis with aqueous KOH form unstable gem-diols, which lose water to give carbonyl compounds.
First hydrolysis gives: The gem-diol is unstable and converts to acetaldehyde: Hence, this produces acetaldehyde.
- Therefore, the correct option is:
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