JEE MainChemistryElectrochemistryMCQ+4 / −1
Given the data at 25oC, + + e- , Eo = 0.152 V + e-, Eo = -0.800 V What is the value of log Ksp for ? (2.303 RT/F = 0.059 V)
- A–8.12
- B+8.612
- C–37.83
- D–16.13
View written solutionFree
Correct answer: D
- Write the given half-reactions
We are given:
We need to find for:
- Obtain the reaction for formation of from and
Reverse reaction (ii):
Now add it to reaction (i):
On adding, and cancel:
For this reaction,
- Relate to equilibrium constant
For the reaction
number of electrons transferred is .
Using
we get
So,
Here is the equilibrium constant for:
But
because
has equilibrium constant .
Therefore,
- Final answer
So the correct option is D.
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