Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Electrochemistry question

2004 · Shift 0 · Q40
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Electrochemistry
  5. /2004 · Shift 0 · Q40

Electrochemistry question

2004 · Shift 0 · Q40

JEE MainChemistryElectrochemistryMCQ+4 / −1
The EM3+/M2+oE_{{M^{3 + }}/{M^{2 + }}}^oEM3+/M2+o​ values for Cr, Mn, Fe and Co are – 0.41, +1.57, + 0.77 and +1.97 V respectively. For which one of these metals the change in oxidation state form +2 to +3 is easiest?
  1. A
    Fe
  2. B
    Mn
  3. C
    Cr
  4. D
    Co
View written solutionFree

Correct answer: C

  1. We are given standard reduction potentials of the type

M3++e−→M2+M^{3+} + e^- \rightarrow M^{2+}M3++e−→M2+

for the metals:

  • Cr3+/Cr2+:E∘=−0.41 V\mathrm{Cr^{3+}/Cr^{2+}} : E^\circ = -0.41\,\text{V}Cr3+/Cr2+:E∘=−0.41V
  • Mn3+/Mn2+:E∘=+1.57 V\mathrm{Mn^{3+}/Mn^{2+}} : E^\circ = +1.57\,\text{V}Mn3+/Mn2+:E∘=+1.57V
  • Fe3+/Fe2+:E∘=+0.77 V\mathrm{Fe^{3+}/Fe^{2+}} : E^\circ = +0.77\,\text{V}Fe3+/Fe2+:E∘=+0.77V
  • Co3+/Co2+:E∘=+1.97 V\mathrm{Co^{3+}/Co^{2+}} : E^\circ = +1.97\,\text{V}Co3+/Co2+:E∘=+1.97V
  1. The question asks: for which metal is the change in oxidation state from +2+2+2 to +3+3+3 easiest?

That corresponds to the oxidation:

M2+→M3++e−M^{2+} \rightarrow M^{3+} + e^-M2+→M3++e−

  1. The given E∘E^\circE∘ values are for the reverse process (reduction):

M3++e−→M2+M^{3+} + e^- \rightarrow M^{2+}M3++e−→M2+

So the oxidation potential for

M2+→M3++e−M^{2+} \rightarrow M^{3+} + e^-M2+→M3++e−

will be the negative of the given reduction potential.

Thus, oxidation is easiest when the reduction potential E∘(M3+/M2+)E^\circ(M^{3+}/M^{2+})E∘(M3+/M2+) is most negative.

  1. Compare the given values:

−0.41,+1.57,+0.77,+1.97-0.41,\quad +1.57,\quad +0.77,\quad +1.97−0.41,+1.57,+0.77,+1.97

The most negative value is:

−0.41 V for Cr-0.41\,\text{V for Cr}−0.41V for Cr

  1. Therefore, Cr2+\mathrm{Cr^{2+}}Cr2+ is most easily oxidized to Cr3+\mathrm{Cr^{3+}}Cr3+.

Hence, the correct option is:

C: Cr\boxed{\text{C: Cr}}C: Cr​

PreviousNext

More from Electrochemistry

  • For a cell reaction involving a two-electron change, the standard e.m.f. of the cell is found to be 0.295 V at 25oC. The equilibrium constant of the reaction at 25oC will be2003 · MCQ
  • Standard reduction electrode potentials of three metals A,B&C are respectively +0.5 V, -3.0 V & -1.2 V. The reducing, powers of these metals are2003 · MCQ
  • When during electrolysis of a solution of AgNO3​, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be :2003 · MCQ
  • For the redox reaction Zn(s) + Cu2+(0.1 M) → Zn2+(1M) + Cu(s) taking place in a cell, Ecello​ is 1.10 volt. Ecell for the cell will be (2.303FRT​ = 0.0591)2003 · MCQ
  • Several blocks of magnesium are fixed to the bottom of a ship to :2003 · MCQ
  • Conductivity (Seimen’s S) is directly proportional to area of the vessel and the concentration of the solution in it and is inversely proportional to the length of the vessel then, then constant of proportionality is expressed in :2002 · MCQ
  • For the following cell with hydrogen electrodes at two different pressure p1 and p2. What will be the emf for the given cell : ​Pt(H2​)∣H+(aq)∣Pt(H2​)p1​1Mp2​​…2002 · MCQ
  • EMF of a cell in terms of reduction potential of its left and right electrodes is :2002 · MCQ