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Coordination Compounds question

2024 · 31 Jan · Shift 1 · Q25
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Coordination Compounds question

2024 · 31 Jan · Shift 1 · Q25

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The 'Spin only' Magnetic moment for [Ni(NH3)6]2+\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}[Ni(NH3​)6​]2+ is ‾\underline{\hspace{2cm}}​×10−1 BM\times 10^{-1} \mathrm{~BM}×10−1 BM. (given === Atomic number of Ni:28\mathrm{Ni}: 28Ni:28)
Numerical answer
View written solutionFree

Correct answer: 28

  1. Find the electronic configuration of Ni\mathrm{Ni}Ni

    Atomic number of Ni=28\mathrm{Ni}=28Ni=28.

    Ni:[Ar] 3d84s2\mathrm{Ni}: [Ar] \, 3d^8 4s^2Ni:[Ar]3d84s2

  2. Find the oxidation state in [Ni(NH3)6]2+[\mathrm{Ni}(\mathrm{NH}_3)_6]^{2+}[Ni(NH3​)6​]2+

    Since NH3\mathrm{NH}_3NH3​ is a neutral ligand,

    Oxidation state of Ni=+2\text{Oxidation state of Ni} = +2Oxidation state of Ni=+2

    So,

    Ni2+:[Ar] 3d8\mathrm{Ni}^{2+}: [Ar] \, 3d^8Ni2+:[Ar]3d8

  3. Determine the number of unpaired electrons

    NH3\mathrm{NH}_3NH3​ is not strong enough here to force pairing in a d8d^8d8 octahedral Ni2+\mathrm{Ni}^{2+}Ni2+ ion beyond the usual arrangement.

    For octahedral d8d^8d8:

    t2g6eg2t_{2g}^6 e_g^2t2g6​eg2​

    This gives:

  • t2g6t_{2g}^6t2g6​ : all paired

  • eg2e_g^2eg2​ : two unpaired electrons

    Hence, number of unpaired electrons,

    n=2n=2n=2

  1. Use spin-only magnetic moment formula

    μ=n(n+2) BM\mu = \sqrt{n(n+2)}\, \text{BM}μ=n(n+2)​BM

    Substituting n=2n=2n=2:

    μ=2(2+2)=8=22≈2.828 BM\mu = \sqrt{2(2+2)} = \sqrt{8} = 2\sqrt{2} \approx 2.828\, \text{BM}μ=2(2+2)​=8​=22​≈2.828BM

  2. Match with the form asked in the question

    The question asks for

    ‾×10−1 BM\underline{\hspace{2cm}} \times 10^{-1}\, \text{BM}​×10−1BM

    Since

    2.828 BM=28.28×10−1 BM2.828\, \text{BM} = 28.28 \times 10^{-1}\, \text{BM}2.828BM=28.28×10−1BM

    As an integer answer, this is taken as:

    28\boxed{28}28​

Comparison with stored answer

Stored correct answer = 282828

Our derived answer = 282828

So, the answer agrees.

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