JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Homoleptic octahedral complexes of a metal ion '' with three monodenate ligands , and adsorb wavelenths in the region of green, blue and red respectively. The increasing order of the ligands strength is :
- A< <
- B< <
- CL1 < L2 < L3
- DL2 < L1 < L3
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Correct answer: A
- For homoleptic octahedral complexes, the color absorbed corresponds to the crystal field splitting energy :
So, larger means smaller absorbed wavelength .
- The ligand strength is directly related to the magnitude of :
- stronger ligand larger
- weaker ligand smaller
- Given absorbed wavelengths:
- absorbs green
- absorbs blue
- absorbs red
In the visible region, wavelength order is:
Therefore, energy order is opposite:
Hence,
- Since ligand strength increases with , the increasing order of ligand strength is:
- Checking options:
- A: ✔
- B: ✘
- C: ✘
- D: ✘
Therefore, the correct option is A.
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