JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1
Ethylamine () can be obtained from N-ethylphatalimide on treatment with :
- A
- B
- C
- D
View written solutionFree
Correct answer: D
-
Identify the reaction involved
-ethylphthalimide is a derivative of phthalimide. To obtain a primary amine from an -alkylphthalimide, the standard method is the Gabriel phthalimide synthesis.
-
Key principle of Gabriel synthesis
In Gabriel synthesis:
- Potassium phthalimide reacts with an alkyl halide to form -alkylphthalimide.
- Then, cleavage of the phthalimide group gives the primary amine.
This cleavage is commonly done using hydrazine .
-
Apply to the given compound
Here, the compound is -ethylphthalimide. On treatment with hydrazine:
Thus, ethylamine is liberated.
-
Check the options
- A: — drying/reducing-type reagent, not used here.
- B: — simple water will not cleave -ethylphthalimide to ethylamine.
- C: — mild reducing agent; not used for Gabriel deprotection.
- D: — correct reagent for hydrazinolysis of -alkylphthalimide.
-
Conclusion
The correct answer is:
More from Compounds Containing Nitrogen
- Which of the following is not a correct method of the preparation of benzylamine from cyanobenzene ?2019 · MCQ
- The major product formed in the reaction given below will be : Includes diagram2019 · MCQ
- The major product of the following reaction is : Includes diagram2019 · MCQ
- An aromatic compound 'A' having molecular formula on treating with aqueous ammonia and heating forms compound 'B'. The compound 'B' on reaction with molecular bromine and potassium hydroxide provides compound 'C' having…2019 · MCQ
- The major product of the following reaction is : Includes diagram2019 · MCQ
- A compound 'X' on treatment with /, provided , which gives positive carbylamine test. Compound 'X' is :2019 · MCQ
- Benzene diazonium chloride on reaction with aniline in the presence of dilute hydrochloric acid gives :2019 · MCQ
- The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is (A) (B) (C) (D) Includes diagram2019 · MCQ