JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1
A compound 'X' on treatment with /, provided , which gives positive carbylamine test. Compound 'X' is :
- A
- B
- C
- D
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Correct answer: A
-
The reagent indicates the Hofmann bromamide reaction.
In this reaction, an amide of type gives a primary amine with one carbon less.
-
The product formed is given as having molecular formula and it gives a positive carbylamine test.
- Carbylamine test is given only by primary amines.
- A primary amine with formula is propylamine .
Therefore, the Hofmann reaction product must be a 3-carbon primary amine.
-
Hence the starting amide must have 4 carbons and be of the form:
-
Now check the options:
A.
- This is butanamide.
- On Hofmann bromamide degradation:
- Product is propylamine, formula , a primary amine.
- Gives positive carbylamine test. ✅
B.
- This is a tertiary amide (no group).
- Hofmann bromamide reaction requires a primary amide.
- So this will not give the required primary amine. ❌
C.
- This is not a proper primary amide structure for Hofmann degradation. ❌
D.
- Also not a primary amide. ❌
-
Therefore, the only suitable compound is:
So, option A is correct.
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