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Chemical Kinetics and Nuclear Chemistry question

2023 · 24 Jan · Shift 2 · Q9
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Chemical Kinetics and Nuclear Chemistry question

2023 · 24 Jan · Shift 2 · Q9

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1

A student has studied the decomposition of a gas AB 3_33​ at 25 ∘^\circ∘ C. He obtained the following data.

p (mm Hg) 50 100 200 400
relative t 1/2_{1/2}1/2​ (s) 4 2 1 0.5

The order of the reaction is

  1. A
    2
  2. B
    0.5
  3. C
    1
  4. D
    0 (zero)
View written solutionFree

Correct answer: A

  1. For a reaction of order nnn, the half-life depends on the initial concentration (or initial pressure for a gas) as:

t1/2∝1a n−1t_{1/2} \propto \frac{1}{a^{\,n-1}}t1/2​∝an−11​

where aaa is the initial concentration/pressure.

Since for a gas at constant temperature,

a∝pa \propto pa∝p

we can write:

t1/2∝p−(n−1)t_{1/2} \propto p^{-(n-1)}t1/2​∝p−(n−1)

  1. From the given data:
  • When ppp doubles from 505050 to 100100100, relative t1/2t_{1/2}t1/2​ changes from 444 to 222.
  • When ppp doubles again from 100100100 to 200200200, t1/2t_{1/2}t1/2​ changes from 222 to 111.
  • When ppp doubles again from 200200200 to 400400400, t1/2t_{1/2}t1/2​ changes from 111 to 0.50.50.5.

So, every time pressure doubles, half-life becomes half.

Thus,

t1/2∝1pt_{1/2} \propto \frac{1}{p}t1/2​∝p1​

  1. Compare with the general relation:

t1/2∝p−(n−1)t_{1/2} \propto p^{-(n-1)}t1/2​∝p−(n−1)

Given:

p−(n−1)=p−1p^{-(n-1)} = p^{-1}p−(n−1)=p−1

Therefore,

n−1=1n-1=1n−1=1 n=2n=2n=2

  1. Hence the reaction is of second order.

So the correct option is:

A: 2\boxed{\text{A: }2}A: 2​

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