JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
A student has studied the decomposition of a gas AB at 25 C. He obtained the following data.
| p (mm Hg) | 50 | 100 | 200 | 400 |
|---|---|---|---|---|
| relative t (s) | 4 | 2 | 1 | 0.5 |
The order of the reaction is
- A2
- B0.5
- C1
- D0 (zero)
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Correct answer: A
- For a reaction of order , the half-life depends on the initial concentration (or initial pressure for a gas) as:
where is the initial concentration/pressure.
Since for a gas at constant temperature,
we can write:
- From the given data:
- When doubles from to , relative changes from to .
- When doubles again from to , changes from to .
- When doubles again from to , changes from to .
So, every time pressure doubles, half-life becomes half.
Thus,
- Compare with the general relation:
Given:
Therefore,
- Hence the reaction is of second order.
So the correct option is:
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