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Chemical Kinetics and Nuclear Chemistry question

2022 · 24 Jun · Shift 1 · Q16
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Chemical Kinetics and Nuclear Chemistry question

2022 · 24 Jun · Shift 1 · Q16

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
The rate constants for decomposition of acetaldehyde have been measured over the temperature range 700 - 1000 K. The data has been analysed by plotting ln k vs 103T{{{{10}^3}} \over T}T103​ graph. The value of activation energy for the reaction is ‾\underline{\hspace{2cm}}​ kJ mol −-− 1. (Nearest integer) (Given : R = 8.31 J K −-− 1 mol −-− 1) JEE Main 2022 (Online) 24th June Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 82 English
Numerical answer
View written solutionFree

Correct answer: 154

  1. Arrhenius equation

    For a reaction, k=Ae−Ea/(RT)k = A e^{-E_a/(RT)}k=Ae−Ea​/(RT)

    Taking natural logarithm: ln⁡k=ln⁡A−EaRT\ln k = \ln A - \frac{E_a}{RT}lnk=lnA−RTEa​​

  2. Form of the graph

    The graph is plotted between ln⁡k\ln klnk and 103T\dfrac{10^3}{T}T103​.

    Let x=103Tx = \frac{10^3}{T}x=T103​ Then, 1T=x103\frac{1}{T} = \frac{x}{10^3}T1​=103x​

    So the Arrhenius equation becomes ln⁡k=ln⁡A−EaR⋅x103\ln k = \ln A - \frac{E_a}{R}\cdot \frac{x}{10^3}lnk=lnA−REa​​⋅103x​

    Hence slope of the graph is m=−Ea1000Rm = -\frac{E_a}{1000R}m=−1000REa​​

  3. Using the slope

    From the given analyzed plot of ln⁡k\ln klnk vs 103T\dfrac{10^3}{T}T103​, the slope is approximately m≈−18.5m \approx -18.5m≈−18.5

    Therefore, Ea=−m(1000R)E_a = -m(1000R)Ea​=−m(1000R)

    Substituting R=8.31 J K−1mol−1R = 8.31\,\text{J K}^{-1}\text{mol}^{-1}R=8.31J K−1mol−1, Ea=18.5×1000×8.31E_a = 18.5 \times 1000 \times 8.31Ea​=18.5×1000×8.31 Ea=153735 J mol−1E_a = 153735\,\text{J mol}^{-1}Ea​=153735J mol−1

  4. Convert to kJ mol−1^{-1}−1

    Ea=153.735 kJ mol−1E_a = 153.735\,\text{kJ mol}^{-1}Ea​=153.735kJ mol−1

    Nearest integer: Ea≈154 kJ mol−1E_a \approx 154\,\text{kJ mol}^{-1}Ea​≈154kJ mol−1

  5. Comparison with stored answer

    Derived answer = 154154154

    Stored correct answer = 154154154

    Both match.

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