JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
The rate constants for decomposition of acetaldehyde have been measured over the temperature range 700 - 1000 K. The data has been analysed by plotting ln k vs graph. The value of activation energy for the reaction is kJ mol 1. (Nearest integer) (Given : R = 8.31 J K 1 mol 1) 

Numerical answer
View written solutionFree
Correct answer: 154
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Arrhenius equation
For a reaction,
Taking natural logarithm:
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Form of the graph
The graph is plotted between and .
Let Then,
So the Arrhenius equation becomes
Hence slope of the graph is
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Using the slope
From the given analyzed plot of vs , the slope is approximately
Therefore,
Substituting ,
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Convert to kJ mol
Nearest integer:
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Comparison with stored answer
Derived answer =
Stored correct answer =
Both match.
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