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Chemical Equilibrium question

2003 · Shift 0 · Q8
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Chemical Equilibrium question

2003 · Shift 0 · Q8

JEE MainChemistryChemical EquilibriumMCQ+4 / −1
Consider the reaction equilibrium 2 SO2SO_2SO2​ (g) + O2O_2O2​ (g) ⇋\leftrightharpoons⇋ 2 SO3SO_3SO3​ (g); ΔHo\Delta H^oΔHo = -198 kJ One the basis of Le Chatelier's principle, the condition favourable for the forward reaction is :
  1. A
    increasing temperature as well as pressure
  2. B
    lowering the temperature and increasing the pressure
  3. C
    any value of temperature and pressure
  4. D
    lowering temperature as well as pressure
View written solutionFree

Correct answer: B

  1. Identify the reaction and heat change

    The equilibrium is: 2SO2(g)+O2(g)⇌2SO3(g),ΔH∘=−198 kJ2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g), \qquad \Delta H^\circ = -198\text{ kJ}2SO2​(g)+O2​(g)⇌2SO3​(g),ΔH∘=−198 kJ

    Since ΔH∘\Delta H^\circΔH∘ is negative, the forward reaction is exothermic.

  2. Effect of temperature using Le Chatelier's principle

    For an exothermic reaction, heat may be treated as a product: 2SO2(g)+O2(g)⇌2SO3(g)+heat2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g) + \text{heat}2SO2​(g)+O2​(g)⇌2SO3​(g)+heat

    If temperature is lowered, the equilibrium shifts in the direction that produces heat, i.e. forward direction.

    So, low temperature favors the forward reaction.

  3. Effect of pressure using Le Chatelier's principle

    Count moles of gaseous reactants and products:

    • Reactant side: 2+1=32 + 1 = 32+1=3 moles of gas
    • Product side: 222 moles of gas

    Increasing pressure shifts equilibrium toward the side with fewer moles of gas.

    Since the product side has fewer moles, high pressure favors the forward reaction.

  4. Combine both conditions

    • Forward reaction is favored by lower temperature
    • Forward reaction is favored by higher pressure

    Therefore, the favorable condition is: lowering temperature and increasing pressure\boxed{\text{lowering temperature and increasing pressure}}lowering temperature and increasing pressure​

  5. Evaluate options

    • A: increasing temperature as well as pressure →\rightarrow→ temperature effect is unfavorable
    • B: lowering the temperature and increasing the pressure →\rightarrow→ both effects favor forward reaction
    • C: any value of temperature and pressure →\rightarrow→ incorrect
    • D: lowering temperature as well as pressure →\rightarrow→ pressure effect is unfavorable

Hence, the correct option is B.

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