- Aincreasing temperature as well as pressure
- Blowering the temperature and increasing the pressure
- Cany value of temperature and pressure
- Dlowering temperature as well as pressure
View written solutionFree
Correct answer: B
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Identify the reaction and heat change
The equilibrium is:
Since is negative, the forward reaction is exothermic.
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Effect of temperature using Le Chatelier's principle
For an exothermic reaction, heat may be treated as a product:
If temperature is lowered, the equilibrium shifts in the direction that produces heat, i.e. forward direction.
So, low temperature favors the forward reaction.
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Effect of pressure using Le Chatelier's principle
Count moles of gaseous reactants and products:
- Reactant side: moles of gas
- Product side: moles of gas
Increasing pressure shifts equilibrium toward the side with fewer moles of gas.
Since the product side has fewer moles, high pressure favors the forward reaction.
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Combine both conditions
- Forward reaction is favored by lower temperature
- Forward reaction is favored by higher pressure
Therefore, the favorable condition is:
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Evaluate options
- A: increasing temperature as well as pressure temperature effect is unfavorable
- B: lowering the temperature and increasing the pressure both effects favor forward reaction
- C: any value of temperature and pressure incorrect
- D: lowering temperature as well as pressure pressure effect is unfavorable
Hence, the correct option is B.
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