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Biomolecules question

2021 · 18 Mar · Shift 1 · Q5
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  5. /2021 · 18 Mar · Shift 1 · Q5

Biomolecules question

2021 · 18 Mar · Shift 1 · Q5

JEE MainChemistryBiomoleculesMCQ+4 / −1
A non-reducing sugar "A" hydrolyses to give two reducing mono saccharides. Sugar A is
  1. A
    Fructose
  2. B
    Galactose
  3. C
    Glucose
  4. D
    Sucrose
View written solutionFree

Correct answer: D

  1. Understand the key terms

    • A non-reducing sugar does not reduce Tollens' or Fehling's reagent.
    • On hydrolysis, if it gives two reducing monosaccharides, we need a disaccharide whose component monosaccharides are reducing.
  2. Check the options

    A. Fructose

    • Fructose is a monosaccharide, not a disaccharide.
    • It does not hydrolyse into two monosaccharides.
    • Hence, not correct.

    B. Galactose

    • Galactose is also a monosaccharide.
    • It cannot hydrolyse into two monosaccharides.
    • Hence, not correct.

    C. Glucose

    • Glucose is a monosaccharide.
    • It also cannot hydrolyse into two monosaccharides.
    • Hence, not correct.

    D. Sucrose

    • Sucrose is a disaccharide made of glucose + fructose.
    • It is non-reducing because both anomeric carbons are involved in the glycosidic linkage.
    • On hydrolysis: Sucrose+H2O→Glucose+Fructose\text{Sucrose} + H_2O \rightarrow \text{Glucose} + \text{Fructose}Sucrose+H2​O→Glucose+Fructose
    • Both glucose and fructose are reducing monosaccharides.
    • Hence, correct.
  3. Conclusion

    The non-reducing sugar that hydrolyses to give two reducing monosaccharides is: Sucrose\boxed{\text{Sucrose}}Sucrose​

  4. Comparison with stored answer

    • Derived answer: D
    • Stored correct answer: D
    • They match.
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