
- A4-methyl-2-nitro-5-oxohept-3-enal
- B4-methyl-5-oxo-2-nitrohept-3-enal
- C4-methyl-6-nitro-3-oxohept-4-enal
- D6-formyl-4-methyl-2-nitrohex-3-enal
View written solutionFree
Correct answer: C
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Identify the principal functional group
The suffix must be chosen from the highest-priority functional group present.
Given the options, the compound contains:
- an aldehyde group, so the parent suffix will be -al,
- a ketone group, which will be written as oxo (prefix),
- a nitro substituent,
- a methyl substituent,
- a double bond.
Therefore, the parent chain must include the aldehyde carbon and be numbered from that carbon as carbon-1.
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Choose the longest chain containing the aldehyde carbon
From the options, the correct parent chain is a 7-carbon chain, so the parent hydrocarbon is heptanal derivative, not hexanal with a formyl substituent unless unavoidable.
Hence option D is not preferred because IUPAC chooses the longest chain containing the principal functional group.
-
Number the chain from the aldehyde carbon
Since aldehyde has highest priority, numbering starts at the aldehyde carbon:
On examining the structure implied by the options, the substituents/unsaturation are placed as:
- double bond at carbon 4: hept-4-enal,
- ketone at carbon 3: 3-oxo,
- methyl at carbon 4: 4-methyl,
- nitro at carbon 6: 6-nitro.
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Write the name in proper IUPAC order
Prefixes are written alphabetically:
- methyl
- nitro
- oxo
But the functional unsaturation and suffix are part of the parent name. Thus the complete name becomes:
-
Check options
- A: -methyl--nitro--oxohept--enal → incorrect locants.
- B: same locants as A, only different ordering → still incorrect.
- C: -methyl--nitro--oxohept--enal → correct.
- D: uses hex chain with formyl substituent, not preferred over longest parent chain containing aldehyde.
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Final answer
The correct IUPAC name is: So the correct option is C.
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