
- A4-methyl-3-ethylhex-4-ene
- B3-ethyl-4-methylhex-4-ene
- C4-ethyl-3-methylhex-2-ene
- D4, 4- diethyl-3-methylbut-2-ene
View written solutionFree
Correct answer: C
-
Identify the longest chain containing the double bond
We must choose the parent chain such that:
- it contains the double bond,
- it is the longest possible chain.
From the given structure, the correct parent chain has 6 carbon atoms and includes the double bond.
Therefore, the parent hydrocarbon is hexene.
-
Number the chain to give the double bond the lowest locant
In IUPAC nomenclature, the double bond gets priority in numbering.
Numbering from the end nearer the double bond gives: and not hex-4-ene, because:
-
Locate the substituents
After numbering the main chain as hex-2-ene, the substituents are:
- one ethyl group at carbon 4,
- one methyl group at carbon 3.
So the substituent positions are:
- -ethyl
- -methyl
-
Arrange substituents alphabetically
In IUPAC naming, substituents are written in alphabetical order:
- ethyl
- methyl
Hence the name becomes:
-
Check options
-
A: 4-methyl-3-ethylhex-4-ene
Incorrect: double bond locant is not lowest. -
B: 3-ethyl-4-methylhex-4-ene
Incorrect: double bond locant is not lowest. -
C: 4-ethyl-3-methylhex-2-ene
Correct. -
D: 4,4-diethyl-3-methylbut-2-ene
Incorrect: does not use the longest valid parent chain.
-
-
Final answer
The correct IUPAC name is:
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