JEE MainChemistryAldehydes Ketones and Carboxylic AcidsNumerical+4 / −1
Two moles of benzaldehyde and one mole of acetone under alkaline conditions using aqueous after heating gives as the major product. The number of bonds in the product is .
Numerical answer
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Correct answer: 9
- Identify the reaction type
Under alkaline conditions, benzaldehyde and acetone undergo cross aldol condensation (Claisen–Schmidt condensation).
- Benzaldehyde: no -hydrogen, so it cannot form enolate.
- Acetone: has -hydrogens, so it forms the enolate.
Since 2 moles of benzaldehyde react with 1 mole of acetone, the condensation occurs on both sides of acetone.
- Write the overall product
First condensation gives benzylidene acetone:
Second condensation with another mole of benzaldehyde gives:
Thus the major product is dibenzalacetone:
- Count the bonds in dibenzalacetone
Structure:
Now count all double bonds:
- Left benzene ring: bonds
- Right benzene ring: bonds
- Two alkene bonds: bonds
- One carbonyl bond: bond
Total:
- Final answer
The number of bonds in the major product is:
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