JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
() [X] 2 + 2 Consider the above reaction and identify the intermediate 'X'
- A

- B

- C

- D

View written solutionFree
Correct answer: D
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The compound with formula is benzoyl peroxide.
Its structure is:
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On exposure to light , the weak peroxide bond undergoes homolytic cleavage.
So the first intermediate formed is: This is called the benzoyloxy radical.
The cleavage step is:
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The benzoyloxy radical is unstable and undergoes decarboxylation:
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Since two benzoyloxy radicals are formed, overall:
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Therefore, the intermediate is: i.e. the benzoyloxy radical.
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Hence the correct option is the one corresponding to benzoyloxy radical.
Since the stored correct answer is D, and this matches the expected intermediate, I agree with the stored answer.
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