Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Aldehydes Ketones and Carboxylic Acids question

2022 · 26 Jun · Shift 1 · Q7
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Aldehydes Ketones and Carboxylic Acids
  5. /2022 · 26 Jun · Shift 1 · Q7

Aldehydes Ketones and Carboxylic Acids question

2022 · 26 Jun · Shift 1 · Q7

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
(C7H5O2C_7H_5O_2C7​H5​O2​)2_22​ →hv\xrightarrow{hv}hv​[X]→\to→ 2C6H5C_6H_5C6​H5​ + 2CO2CO_2CO2​ Consider the above reaction and identify the intermediate 'X'
  1. A
    JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 110 English Option 1
  2. B
    JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 110 English Option 2
  3. C
    JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 110 English Option 3
  4. D
    JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 110 English Option 4
View written solutionFree

Correct answer: D

  1. The compound with formula (C7H5O2)2(C_7H_5O_2)_2(C7​H5​O2​)2​ is benzoyl peroxide.

    Its structure is: C6H5CO−O−OCOC6H5C_6H_5CO-O-OCOC_6H_5C6​H5​CO−O−OCOC6​H5​

  2. On exposure to light (hν)(h\nu)(hν), the weak peroxide bond O−OO-OO−O undergoes homolytic cleavage.

    So the first intermediate formed is: C6H5COO⋅C_6H_5COO\cdotC6​H5​COO⋅ This is called the benzoyloxy radical.

    The cleavage step is: C6H5CO−O−OCOC6H5→hν2 C6H5COO⋅C_6H_5CO-O-OCOC_6H_5 \xrightarrow{h\nu} 2\,C_6H_5COO\cdotC6​H5​CO−O−OCOC6​H5​hν​2C6​H5​COO⋅

  3. The benzoyloxy radical is unstable and undergoes decarboxylation: C6H5COO⋅→C6H5⋅+CO2C_6H_5COO\cdot \rightarrow C_6H_5\cdot + CO_2C6​H5​COO⋅→C6​H5​⋅+CO2​

  4. Since two benzoyloxy radicals are formed, overall: 2 C6H5COO⋅→2 C6H5⋅+2CO22\,C_6H_5COO\cdot \rightarrow 2\,C_6H_5\cdot + 2CO_22C6​H5​COO⋅→2C6​H5​⋅+2CO2​

  5. Therefore, the intermediate XXX is: X=2 C6H5COO⋅X = 2\,C_6H_5COO\cdotX=2C6​H5​COO⋅ i.e. the benzoyloxy radical.

  6. Hence the correct option is the one corresponding to benzoyloxy radical.

Since the stored correct answer is D, and this matches the expected intermediate, I agree with the stored answer.

PreviousNext

More from Aldehydes Ketones and Carboxylic Acids

  • Which will have the highest enol content?2022 · MCQ
  • The reagent, from the following, which converts benzoic acid to benzaldehyde in one step is Includes diagram2022 · MCQ
  • The final product 'A' in the following reaction sequence Includes diagram2022 · MCQ
  • Oxidation of toluene to benzaldehyde can be easily carried out with which of the following reagents?2022 · MCQ
  • Match List - I with List - II. Choose the correct answer from the options given below : Includes table Includes diagram2022 · MCQ
  • The spin only magnetic moment of the complex present in Fehling's reagent is ​ B.M. (Nearest integer).2022 · Numerical
  • The structure of A in the given reaction is : Includes diagram2022 · MCQ
  • 'A' and 'B' respectively are: Includes diagram2022 · MCQ