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Aldehydes Ketones and Carboxylic Acids question

2021 · 26 Feb · Shift 2 · Q11
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Aldehydes Ketones and Carboxylic Acids question

2021 · 26 Feb · Shift 2 · Q11

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
2, 4-DNP test can be used to identify :
  1. A
    ether
  2. B
    amine
  3. C
    aldehyde
  4. D
    halogens
View written solutionFree

Correct answer: C

  1. What is the 2,4-DNP test?

    The reagent 2,42,42,4-dinitrophenylhydrazine (also called Brady’s reagent) is used to test for the presence of a carbonyl group in aldehydes and ketones.

  2. Reaction involved

    Aldehydes and ketones react with 2,42,42,4-DNP to form 2,4-dinitrophenylhydrazones, usually giving a yellow/orange precipitate:

    RCHO or RCOR’+2,4-DNP→hydrazone precipitate\text{RCHO or RCOR'} + \text{2,4-DNP} \rightarrow \text{hydrazone precipitate}RCHO or RCOR’+2,4-DNP→hydrazone precipitate

  3. Check each option

    • A: ether — Ethers do not contain a carbonyl group, so they do not give the 2,42,42,4-DNP test.
    • B: amine — Amines also do not contain a carbonyl group, so they do not give this test.
    • C: aldehyde — Aldehydes contain the carbonyl group (−CHO)(-CHO)(−CHO), so they do give the 2,42,42,4-DNP test.
    • D: halogens — Halogens are identified by different tests, not by 2,42,42,4-DNP.
  4. Conclusion

    Since this is a single-correct MCQ, the correct option is:

    C: aldehyde\boxed{\text{C: aldehyde}}C: aldehyde​

  5. Comparison with stored correct answer

    Stored correct answer = C

    Derived answer = C

    Therefore, the derived answer agrees with the stored correct answer.

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