JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Which one of the following reduced with zinc and hydrochloric acid to give the corresponding hydrocarbon?
- AEthyl acetate
- BButan -2-one
- CAcetamide
- DAcetic acid
View written solutionFree
Correct answer: B
-
We need to identify which compound gives the corresponding hydrocarbon on reduction with zinc and hydrochloric acid.
-
The reagent combination Zn/HCl is used in Clemmensen reduction, which reduces:
In general:
Even when written as Zn/HCl in such questions, the intended reaction is the Clemmensen-type reduction of the carbonyl group.
-
Now check each option:
A. Ethyl acetate
- It is an ester:
- Esters are not reduced to hydrocarbons by Zn/HCl.
- So, incorrect.
B. Butan-2-one
- It is a ketone:
- Ketones undergo Clemmensen reduction to hydrocarbons:
- Product is butane, the corresponding hydrocarbon.
- So, correct.
C. Acetamide
- It is an amide:
- Amides do not give the corresponding hydrocarbon with Zn/HCl.
- So, incorrect.
D. Acetic acid
- It is a carboxylic acid:
- Carboxylic acids are not reduced to hydrocarbons by Zn/HCl.
- So, incorrect.
-
Therefore, the only compound that gives the corresponding hydrocarbon on reduction with Zn/HCl is:
-
Comparison with stored correct answer:
- Derived answer: B
- Stored correct answer: B
- They match.
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