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Alcohols Phenols and Ethers question

2024 · 27 Jan · Shift 2 · Q9
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Alcohols Phenols and Ethers question

2024 · 27 Jan · Shift 2 · Q9

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
Phenolic group can be identified by a positive:
  1. A
    Tollen's test
  2. B
    Phthalein dye test
  3. C
    Carbylamine test
  4. D
    Lucas test
View written solutionFree

Correct answer: B

  1. Identify what is being asked

    We need the test that gives a positive result for a phenolic group.

  2. Check each option

    A: Tollen's test

    • Tollen's reagent is used mainly to detect aldehydes.
    • It gives a silver mirror with aldehydes.
    • Phenols do not generally give Tollen's test.

    Therefore, A is incorrect.

    B: Phthalein dye test

    • Phenols react with phthalic anhydride in presence of concentrated H2SO4\mathrm{H_2SO_4}H2​SO4​ to form phthalein dyes.
    • This is a characteristic test for phenolic compounds.

    Therefore, B is correct.

    C: Carbylamine test

    • Carbylamine test is given by primary amines.
    • It produces foul-smelling isocyanides.
    • Phenols do not respond to this test.

    Therefore, C is incorrect.

    D: Lucas test

    • Lucas test distinguishes primary, secondary, and tertiary alcohols.
    • It is not a test for phenols.

    Therefore, D is incorrect.

  3. Conclusion

    The phenolic group is identified by a positive phthalein dye test.

    Hence, the correct option is: B\boxed{\text{B}}B​

  4. Comparison with stored correct answer

    • Derived answer: B
    • Stored correct answer: B

    Both match.

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